<p><strong>Abstract.</strong> Black carbon (BC), from the incomplete combustion sources (mainly fossil fuel, biofuel and open biomass burning), is chemically inertness and optical absorbance in the atmosphere. It has significant impacts on global climate, regional air quality, and human health. During the transportation, its physical-chemical characteristics, optical properties and sources would change dramatically. To investigate the BC properties (i.e., mass concentration, sources and optical properties) during the intra-regional transport between the south edge of North China Plain (SE-NCP) and Central China (CC), simultaneous observations of BC at a megacity (Wuhan, WH) in CC, three borderline cities (Xiangyang, XY, Suixian, SX and Hong'an, HA, distributing from the west to east) between SE-NCP and CC and a city (Luohe, LH) in SE-NCP were conducted during the typical winter haze episodes. Using Aethalometer, the highest equivalent BC (eBC) mass concentrations and aerosol absorption coefficients (&#963;<sub>abs</sub>) were found in the city (LH) at SE-NCP, followed by the borderline cities (XY, SX and HA) and megacity (WH). The levels, sources, optical properties (i.e., &#963;<sub>abs</sub> and absorption &#197;ngstr&#246;m exponent, AAE) and geographic origins of eBC were different between clean and pollution episodes. Compared to clean days, the higher eBC levels (increased by 26.4&#8211;163&#8201;%) and &#963;abs (increased by 18.2&#8211;236&#8201;%) were found during pollution episodes due to more combustion of fossil fuel (contributing for 51.1&#8211;277&#8201;%), supported by the decreased AAE (by 7.40&#8211;12.7&#8201;%). Non-parametric wind regression (NWR) and concentration-weighted trajectory (CWT) results showed that the geographic origins of biomass burning (BC<sub><i>bb</i></sub>) and fossil fuel (BC<sub><i>ff</i></sub>) combustion derived BC were different. Based on cluster analysis of trajectories, air parcels from south direction dominated for border sites during clean days, with contributions of 46.0&#8211;58.2&#8201;%, while trajectories from the northeast had higher contributions (37.5&#8211;51.2&#8201;%) during pollution episodes. At the SE-NCP site (LH), transboundary influences from south direction (CC) exhibited more frequent impact (with the air parcels from this direction contributed 47.8&#8201;% of all the parcels) on the ambient eBC levels during pollution episodes. At WH, eBC was mainly from the northeast transport route during the whole observation period. Two transportation cases showed that from upwind to downwind direction, the mass concentrations of eBC, BC<sub><i>bb</i></sub> and BC<sub><i>ff</i></sub> all increased, while AAE decreased. This study highlighted that intra-regional prevention and control for dominated sources of specific sites should be considered to improve the regional air quality.</p>