Due to extensive groundwater exploitation, a groundwater funnel has persisted in the Hutuo River alluvial fan in Shijiazhuang since the 1980s, lasting nearly 40 years and significantly impacting the groundwater chemical characteristics. In this study, based on the groundwater level and chemistry data, the hydrochemical evolution processes and mechanisms of the groundwater during the 1980 groundwater funnel period and the post-2015 artificial governance period were investigated using traditional hydrogeochemical methods and inverse hydrogeochemical simulations. The results show the following: (1) The ion concentrations gradually increased along the groundwater flow path, where they displayed a pattern of lower levels in the northwest and higher levels in the southeast. From 1980 to 2021, the concentrations of major ions were increased. (2) In 1980s, the groundwater hydrochemical type predominantly exhibited HCO3—Ca. From 1980 to 2015, the hydrochemical types diversified into HCO3·Cl—Ca, HCO3—Ca·Mg, and HCO3·SO4—Ca types. Following the artificial governance, the groundwater level rise led to an increase in the concentrations of SO42− and Mg2+. Post-2015, the prevailing hydrochemical type changed to HCO3·SO4—Ca·Mg. (3) The changes in the groundwater level and ion concentrations were quantitatively strongly correlated and exhibited spatial similarity. (4) In the 1980s, the groundwater hydrochemical composition was primarily controlled by the dissolution of albite, dolomite, halite, and quartz; reverse cation exchange; and groundwater exploitation. Since 2015, the hydrochemical composition has mainly been influenced by the dissolution of albite, calcite, and quartz; positive cation exchange; river–groundwater mixing; and industrial activities, with increasing intensities of both water–rock interactions and human activities.
