“…In our case, we consider only the temperature of the reactor, T r , and of the jacket, T j : q̇ acc = C p , r d T r d t + C p , j d T j d t C p, r is the total heat capacity of the bulk [J/K], and C p, j is the total heat capacity of the calorimeter [J/K], including the jacket and the vessel, commonly called calorimeter constant . C p, r is calculated experimentally with temperature oscillation calorimetry, and C p, j is calibrated from an experiment without chemical reaction, applying a temperature ramp. The derivatives of the temperatures were calculated employing a Savitzky−Golay filter, with the following parameters: 121 data points, corresponding to 12.1 s of experiment, and a sixth-order polynomial fit.…”