In
the fuel cooling system of an engine, the heating of aviation
kerosene causes it to exhibit complicated, unsteady physicochemical
processes and forms undesirable coke deposition. To understand these
processes better, we investigated the coupling relationship between
turbulent flow, heat transfer, autoxidation, and deposition reactions
of fuel in a cooling heat exchanger. The experiments were performed
to investigate the whole process within 105 min, separated into five
continuous phases of 20, 40, 60, 80, and 105 min, with a heat flux
of 38.6 kW/m2. On the basis of the experimental results,
we established a three-dimensional model to study the influence of
kerosene’s heat-transfer process on oxidation deposition in
a long, straight, horizontal pipe under supercritical pressure condition.
A modified six-step, pseudo-detailed chemical kinetic and global deposition
mechanism has been incorporated into the numerical model with particular
attention to temperature variation. The model was validated based
on the quantity of deposition and dissolved oxygen consumption rate
under different experimental temperatures and heating times. We then
analyzed the fluid dynamics profiles and physical parameters of density,
specific heat, viscosity, and Reynolds number, species, and deposition
rates along the reactor, micrographs, and surface elements of deposition
at various temperatures to understand the coupling effect between
heat transfer and coke deposition. The results indicated that supercritical
characteristics of both the fuel and deposition affect the local heat-transfer
characteristics, resulting in some instabilities in the wall temperature
distribution. The fuel temperature determines the regime of the chemical
reactions in the flow, and the flow conditions and wall temperature
determine the deposition rate at the local position of the inner surface.