1984
DOI: 10.1246/bcsj.57.3052
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Temperature Effect on Decay of Ions and Radicals in Supercooled Liquids as Studied by Pulse Radiolysis and γ-Radiolysis: 1-Propanol and Ethanol

Abstract: The decay-rate constants, k, of dipentyl disulfide anions or benzyl radicals in 1-propanol and ethanol were measured over a temperature range of 107–230 K by pulse- and γ-radiolysis method. The decay-rate constants were found to range over nine orders of magnitude. The decay kinetics is a composite first-order reaction. Since the decay rates of reaction intermediates observed are diffusion-controlled, the decay-rate constants represent directly the rates of molecular transport in the supercooled liquids. It wa… Show more

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