Temperature Dependence of Conductance of Electrolytes in Nonaqueous Solutions

Ionic Liquids in Microemulsions—A Concept To Extend the Conventional Thermal Stability Range of Microemulsions

“…It was first described by Robinson and Stokes 201 and experimentally verified by Barthel and coworkers. 198,200 For capillary cells β was found to be -3.5·10…”

Conductivity and Interparticle Interactions in the Solutions of 1-1 Electrolytes in Propylene Carbonate in the Wide Range of Temperatures

“…Purity was controlled by specific electrical conductivity, κ 298.15 = 3.2⋅10 -8 Sm•cm -2 , and moisture presence -by Fisher method of coulometric titration (water content did not exceed 0.003 %). Physical and chemical properties of the solvent at various temperatures were found from the following polynomials described in the work [26] Table 2.…”

A potentiometric study of (acid + base) equilibria in substituted 4-nitropyridine N-oxide systems in methanol and dimethyl sulfoxide

“…Also in this work, the potentiometric method was used as a basic technique for the investigation of (acid + base) equilibria. The principal aim of this study was to determine the pK a values and cationic homoconjugation constants in (acid + base) systems formed by a variety of substituted 4-nitropyridine N-oxides in polar non-aqueous solvents, the amphiprotic methanol of moderate basicity (donicity number, DN = 19.1 [22]), and the strongly basic aprotic protophilic dimethyl sulfoxide (DN = 29.0 [22]). Methanol (MeOH) as a solvent almost isoelectric in relation to acetonitrile (AN) and nitrobenzene (NM) and highly polar dimethyl sulfoxide (DMSO) has been chosen to avoid potential complications associated with establishing of intricate association equilibria as was the case with weak polar solvents.…”