We investigate physical properties of bromoform (liquid CHBr3) including compressibility and refractive index under dynamic extreme conditions of shock compression. Planar shock experiments are conducted along with high-speed laser interferometry. Our experiments and previous results establish a linear shock velocity−particle velocity relation for particle velocities below 1.77 km/s, as well as the Hugoniot and isentropic compression curves up to ∼21 GPa. Shock-state refractive indices of CHBr3 up to 2.3 GPa or ∼26% compression, as a function of density, can be described with a linear relation and follows the Gladstone-Dale relation. The velocity corrections for laser interferometry measurements at 1550 nm are also obtained.