Telechelic Syntheses of the First Phosphazene Siloxane Block Copolymers

Prange, Robbyn; Allcock, Harry R.

doi:10.1021/ma991136o

Cited by 59 publications

(46 citation statements)

References 14 publications

(9 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…4. Synthesis of poly(dichlorophosphazene) from linear chlorophosphazene monomers, followed by chlorine replacement at the macromolecular level [28][29][30][31][32][33][34][35][36]. 5.…”

Section: Basic Polymer Synthesis Processesmentioning

confidence: 99%

Expanding Options in Polyphosphazene Biomedical Research

Allcock

2008

Polyphosphazenes for Biomedical Applications

Self Cite

View full text Add to dashboard Cite

“…4. Synthesis of poly(dichlorophosphazene) from linear chlorophosphazene monomers, followed by chlorine replacement at the macromolecular level [28][29][30][31][32][33][34][35][36]. 5.…”

Section: Basic Polymer Synthesis Processesmentioning

confidence: 99%

Expanding Options in Polyphosphazene Biomedical Research

Allcock

2008

Polyphosphazenes for Biomedical Applications

Self Cite

View full text Add to dashboard Cite

“…a reactive polymeric intermediate (4) by organic groups. These processes are illustrated in Scheme 1 [5][6][7][8][9][10][11][12][13][14][15][16].…”

Section: Hydrophobic Polyphosphazenesmentioning

confidence: 99%

Hydrophobic and Superhydrophobic Polyphosphazenes

Allcock

Steely

Singh

et al. 2009

Journal of Adhesion Science and Technology

Self Cite

View full text Add to dashboard Cite

Polyphosphazenes are a class of hybrid organic-inorganic polymers that have good solubility in classical organic solvents and are thermo-oxidatively stable. Over the years, poly(dichlorophosphazene) has been used as a macromolecular intermediate to yield a number of polymers which can be hydrophobic or superhydrophobic. This review deals with several classical hydrophobic polyphosphazenes such as poly(bis-2,2,2-trifluoroethoxyphosphazene), species with siloxane containing substituents and phosphazene graft polymers. Poly(phosphazophosphazenes) and phenoxy-substituted polyphosphazenes are some of the more recent polymers that have been examined for their hydrophobic character. Processing methods such as electrospinning can enhance the hydrophobicity of polyphosphazenes to move them into the realm of superhydrophobic materials. Many polymers which are only borderline hydrophobic can now be converted into superhydrophobic materials by the use of environmental plasma treatment.

show abstract

“…The partial aminolysis and alcoholysis of 1 with methylamine and tertbutylamine [16], diisopyropylamine [17], o-dichloro and o-dimethylphenol [18], 2,4,6-tert-butylphenol and 2,6-di-tert-butyl-4-methylphenol [19], and allyl alcohol [20] have been reported. These molecules can be used as structural models for phosphazene polymers with a large range of properties [2,21] and applications [22][23][24][25][26][27][28][29].…”

Section: Introductionmentioning

confidence: 99%