Chemical compositions of 96 natural gas samples from various locations and gas sources at 67 sampling sites in Japan were analyzed. A gas chromatograph system was developed for precise analyses of concentra tions of N2, CH4, C02, 02, Ar, He, Ne, H2, C2H6 and H2S. Overall analytical errors were estimated to be less than 5% for most samples. A sampling reservoir was newly designed in this work. Main components of natural gas samples were C02, N2 and CH4. Whereas N2 showed positive correlations with 4He and 3He concentrations, CO2 and CH4 showed negative correlations with them. Either a mechanism of dilution of the N2 gas enriched in magmatic He by CO2 and/or CH4, or of dissipation of CO2 from magmatic fluid was suggested. Concentrations of Ar and Ne were high in N,2-rich gas samples. Ratios Ne/N2 and Ar/N2 imply the presence of N2 of non-atmospheric origin. The close relationship between CO2 discharge and volcanic activities was pointed out. A possible source of CO2 is carbonates of sedimentary rocks from which CO2 may be released either by pyrolysis or by decomposition due to magmatic activity. Nitrogen and CO2 derived from oceanic sediments may be included in Japanese natural gases associated with subduction of a down-going slab.
INTRODUCTIONThe JapaneseIslands are located in the subduction zone of the circum-Pacific orogenic belt. Geophysical features of NE Japan represent a typical island arc system. More than 2,000 hot springs and mineral springs are distributed in the islands and from some of them bubble gases are released.Gases are released also from gas and oil fields.Natural gases studied in this work include various types of occurrence, such as gases emerged from above sources. Chemical composition data on natural gases provide useful information regarding their origin, primordial volatiles of the Earth, and the evolution of the atmosphere.Chemical studies of natural gases started in 1900's (Moureu, 1904(Moureu, , 1923Yamada, 1922;Pencheff, 1929). Since 1960's, a number of data have been reported with the progress in gas chromatography (Gunter and Musgrave, 1966; Maki et al., 1966;Inai et al., 1967) It is difficult to determine Ne with ordinary gas chromatographic technique owing to its retention time close to that of He and low sen sitivity. Kawabe et al. (1981) reported Ne values in terms of Ne/Ar or Ne/N2 ratio using a 11 12 A. Urabe et al.TCD (thermal conductivity detector) gas chromatograph with He carrier gas. Sensitivity of Ne on the TCD, however, is not high enough to analyze samples with low Ne concentrations. Sugisaki et al. (1982) separated He from Ne in atmospheric samples using an 8-m MS 5A column.The method, however, is not ap propriate for natural gas analyses, because He/ Ne ratios in natural gases are generally 2 to 3 orders of magnitude higher than those of the atmosphere, which would result in insufficient separation of Ne from He.In this study a USD (ultrasonic detector)gas chromatograph with He carrier gas was used for the Ne determination.The USD is particu larly effective to det...