Abstract:Production of energy or chemicals from biomass and several waste substrates appears a concrete strategy for replacing fossil fuels and reducing carbon dioxide emissions in the atmosphere. In particular, methanol from biomass or bio-waste is considered a reliable energy vector and key intermediate for industrial chemistry. Currently, methanol is industrially produced via syngas conversion using natural gas as the main feedstock. Biomethane produced via anaerobic digestion (AD) of Organic Fraction Municipal Soli… Show more
“…This sequence allows to take advantage of the faster conversion rate in the HTS path and to finally approach a higher equilibrium conversion value (larger than 99%) for the most favourable equilibrium conditions in the LTS. The pressure of WGS unit was assumed equal to the pressure of methanol synthesis, which was set at 80 bar [15].…”
Section: Co+h2o=co2+h2mentioning
confidence: 99%
“…Syngas can be produced also by non-fossil sources. For instance, gasification of biomass or waste (thermal or catalytic) is a sustainable way to produce syngas [11][12][13][14][15]. After syngas production, DME synthesis can be performed in two different ways.…”
DME is considered a valuable energy vector, as it may be produced from biomass or waste and it may be used as alternative fuel. DME is currently produced from fossil sources, such as coal or natural gas. The utilization of streams derived from waste management as carbon source for producing chemicals is a reliable strategy for replacing fossil fuels and reducing carbon dioxide emissions in the atmosphere. In this work, a techno-environmental assessment for dimethyl ether production from digestate of organic fraction of municipal solid waste is presented and discussed. In particular, the indirect synthesis of dimethyl ether was assessed by considering the syngas produced via gasification of digestate. The carbon footprint calculated shows an environmental benefit equal to 1.1 kgCO2eq/MJ.
“…This sequence allows to take advantage of the faster conversion rate in the HTS path and to finally approach a higher equilibrium conversion value (larger than 99%) for the most favourable equilibrium conditions in the LTS. The pressure of WGS unit was assumed equal to the pressure of methanol synthesis, which was set at 80 bar [15].…”
Section: Co+h2o=co2+h2mentioning
confidence: 99%
“…Syngas can be produced also by non-fossil sources. For instance, gasification of biomass or waste (thermal or catalytic) is a sustainable way to produce syngas [11][12][13][14][15]. After syngas production, DME synthesis can be performed in two different ways.…”
DME is considered a valuable energy vector, as it may be produced from biomass or waste and it may be used as alternative fuel. DME is currently produced from fossil sources, such as coal or natural gas. The utilization of streams derived from waste management as carbon source for producing chemicals is a reliable strategy for replacing fossil fuels and reducing carbon dioxide emissions in the atmosphere. In this work, a techno-environmental assessment for dimethyl ether production from digestate of organic fraction of municipal solid waste is presented and discussed. In particular, the indirect synthesis of dimethyl ether was assessed by considering the syngas produced via gasification of digestate. The carbon footprint calculated shows an environmental benefit equal to 1.1 kgCO2eq/MJ.
“…This work aims to give new insights and revise the results presented by Giuliano et al [1]. In particular, three different scenarios for bio-methanol production are assessed involving anaerobic digestion as a master unit coupled with side technologies as biomass gasification, carbon capture and water electrolysis, with the scope to give new perspectives for energy savings and greenhouse gas emission mitigation for methanol production, being methanol a candidate as carrier of the future energy economy.…”
Section: Co+2h2=ch3ohmentioning
confidence: 99%
“…The introduction of renewable energy in the chemical production chain is a key element to reduce the carbon and environmental footprint. In this concern, methanol may be considered as a suitable protagonist of this strategy, as reported elsewhere [1,2]. Methanol may be used as a building block for the synthesis of several high-added values products, by both traditional process of industrial chemistry, e.g.…”
The anaerobic digestion (AD) of organic fraction municipal solid wastes (OFMSW) is a well-known technology for the valorization of wastes with the production of biogas, the latter usually used in power plant. Nevertheless, more and more effort is necessary in order to produce energy and chemicals from renewables as a strategy for replacing fossil fuels and reducing carbon dioxide in the atmosphere. In particular, methanol is considered as a promising energetic vector of the future since it may be produced from renewables and it may be used as a reactant for fuels and chemical production. Currently, methanol is industrially produced via syngas conversion using natural gas as the main feedstock. Biomethane produced in AD unit may be used as an alternative to natural gas for production of syngas that may be used for methanol production. In this work, a techno-environmental assessment for methanol production from biogas is presented and discussed, with focusing on the effect of side-unit, e.g. biomass gasification, carbon dioxide capture and renewable hydrogen production, on the environmental impact. Results show that highest CO2 saving is calculated for the biomass-integrated plant, although more detailed investigations, e.g. cost analysis, need for a proper assessment.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.