A direct statistical method has been applied to determine the effect of uncertainties in rate coefficients on computed densities of E region species. Uncertainties in rate coefficients are described in terms of Gaussian error law distributions with a common fractional standard deviation. Mean densities are found to be relatively insensitive to rate coefficient uncertainties; fractional standard deviations of density distributions are, in general, less than twice those associated with rate coefficient distributions, provided the fractional standard deviations of the rate coefficient distributions are not greater than 0.45.
Many reactionsare necessary to describe chemical proces•ses in the atmosphere. In such chemical systems it is difficult to evaluate inaccuracies in the computed species densities. These inaccuracies stem from uncertainties in the input data and from omissions or approximations of relevant physical and chemical processes. One of the uncertainties, that associated with reaction rate coefficients, is treated here by a direct statistical method for the case of an E region chemical reaction system operating over short time intervals. The calculations presented here are meant to be illustrative rather than exhaustive. Sufficient information about the errors and the distribution of errors associated with measurements of rate coefficients is not generally available. Accordingly, in the calculations described here, uncertainties in the rate coefficients were assumed to be describable in terms of the Gaussian error law with a mean value of the rate coefficient ko and a standard deviation s; the effects of variations in s on species densities and their distributions were examined. For simplicity a common fractional standard deviation was assigned to the rate coeffici6nt distributions. Consider a system consisting of n reactions and corres. ponding rate coefficients; let m(