“…Proton tautomerism plays an important role in many fields of chemistry and biochemistry [1][2][3][4][5]. Molecules giving rise to excited state tautomers by intramolecular proton transfer enjoy applications as laser dyes, in higher energy radiation detectors and molecular memory storage devices, as fluorescent probes and also as polymer protecting agents [6].…”
The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations.
“…Proton tautomerism plays an important role in many fields of chemistry and biochemistry [1][2][3][4][5]. Molecules giving rise to excited state tautomers by intramolecular proton transfer enjoy applications as laser dyes, in higher energy radiation detectors and molecular memory storage devices, as fluorescent probes and also as polymer protecting agents [6].…”
The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations.
“…Schiff bases of salicylaldehyde with amines (anils) comprise ac hemical system undergoing hydrogen-atom tautomerism between enol and keto forms and show the phenomena of solid state photochromism and thermochromism [1][2][3].…”
“…Aloe is an active and frequently used ingredient in hundreds of skin lotions, sun blocks for UV protection, and different cosmetics for its cosmetic and healing properties [1][2][3][4][5][6][7][8][9][10][11]. Numerous Aloe species around the world are used in conditions ranging from dermatitis to cancer [1][2][3].…”
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