Targeted synthesis of micro–mesoporous hybrid material derived from octaphenylsilsesquioxane building units

Jing, Xiaofei; Sun, Fuxing; Ren, Hao; Tian, Yuyang; Guo, Mingyi; Li, Lina; Zhu, Guangshan

doi:10.1016/j.micromeso.2012.07.048

Cited by 41 publications

(31 citation statements)

References 50 publications

(64 reference statements)

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“…TGA results (Figure 2b) show that the decomposition temperature is typically higher than 480 o C, with the maximum weight loss at about 570 o C. Surprisingly, the residual weights at 1000 o C for HBPBA-1, -2 and -3 were up to 58, 62, and 63wt% of its original weight, respectively, far more than any commonly known polymers would endure. Upon heating the samples at 300 o C in air for 2 h, we found no significant changes in structure ( Figure S4) or N 2 physisorption properties (Table S3), further confirming their excellent thermal-performance, superior to most MOPs (Table S4) [7,16,17]. In addition to thermal stability, HBPBAs show superior chemical stability.…”

Section: Resultsmentioning

confidence: 56%

Microporous organic polymers based on hexaphenylbiadamantane: Synthesis, ultra-high stability and gas capture

Guo

Lai

et al. 2017

Materials Letters

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This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting galley proof before it is published in its final citable form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.

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Section: Resultsmentioning

confidence: 56%

Microporous organic polymers based on hexaphenylbiadamantane: Synthesis, ultra-high stability and gas capture

Guo

Lai

et al. 2017

Materials Letters

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“…[11,22,25,38a] Moreover, a small broad diffraction peak at about 2θ = 40°is observed, which arises from residual Pd. [40] Additionally, no clear peak is observed at 2θ = 0.5-5°in Figure 6 (a). Furthermore, to observe the particle size and morphology of cage polymer 1 intuitively, field-emission scanning electron microscopy (FE-SEM) was performed ( Figure 7).…”

Section: Resultsmentioning

confidence: 92%

“…[22] The appearance of the Q n [Si(OSi) n (OH) 4-n ] signals centered at δ = -105.5 ppm suggest that the Si-C bonds are partially cleaved. [40] This may arise from the basic environment employed in the crosslinking process. However, it is noteworthy that the ratio of T 3 /(T 3 + Q n ) is relatively high and up to 0.84, which indicates that the overwhelming majority of the SQ cages are retained in the network of cage polymer 1.…”

Section: Resultsmentioning

confidence: 99%

An Efficient Approach to Octabromophenylethyl‐Functionalized Cage Silsesquioxane and Its Use in Constructing Hybrid Porous Materials

Jiang

Yang

et al. 2015

Eur J Inorg Chem

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Octabromophenylethyl-functionalized silsesquioxane (BrPh-SQ) was synthesized by the Friedel-Crafts alkylation of octavinylsilsesquioxane (OVS) with bromobenzene, which acted as both the solvent and reactant and, furthermore, could be recycled after the reaction. The approach possesses the advantages of being mild, economic, and highly efficient. Further, BrPh-SQ was used as a building block in Heck reactions

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“…5.16b). Since then, various synthetic strategies have been used to synthesize CMPs, such as Yamamoto [132][133][134][135][136], Ullmann [137], Suzuki [138][139][140][141][142][143][144][145], Sonogashira-Hagihara coupling [146][147][148][149][150][151][152], oxidative coupling [145,153], and ethynyl cyclotrimerization [154][155][156]. As a result, the CMPs family was expanded quickly in the last several years.…”

Section: Conjugated Microporous Polymersmentioning

confidence: 99%

Microporous Organic Polymers for Carbon Dioxide Capture

Luo

Tan

2014

Green Chemistry and Sustainable Technology

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Microporous organic polymers (MOPs) are a unique class of porous materials consisting solely of the light elements (C, H, O, N, etc.). A series of vivid characteristics of MOPs, such as high-specific surface area, good physicochemical stability, diverse pore dimensions, topologies, and chemical functionalities, make them suitable adsorbents for CO 2 capture. In this chapter, MOPs are categorized into four classes according to the types of organic reactions and the chemical structures of the resulting materials: hypercrosslinked polymers (HCPs), covalent organic frameworks (COFs), polymers of intrinsic microporosity (PIMs), and conjugated microporous polymers (CMPs). For each type of the polymer network, the state-of-the-art development in the design, synthesis, characterization, and the CO 2 sorption performance is reviewed. Strategies for controlling CO 2 uptake capacity and adsorption enthalpy via manipulation of surface area, pore size, and functionality are discussed in detail. These studies would open up many new possibilities for the development of the novel solid sorbents targeting the CO 2 capture process. It is expected that this chapter will not only summarize the main research activities in this field, but also find possible links between basic studies and practical applications. Abbreviations ACMPAcetylene gas mediated conjugated microporous polymers BA Benzyl alcohol BC Benzyl chloride BCMA 9,10-Bis(chloromethyl)anthracene

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Targeted synthesis of micro–mesoporous hybrid material derived from octaphenylsilsesquioxane building units

Cited by 41 publications

References 50 publications

Microporous organic polymers based on hexaphenylbiadamantane: Synthesis, ultra-high stability and gas capture

Microporous organic polymers based on hexaphenylbiadamantane: Synthesis, ultra-high stability and gas capture

An Efficient Approach to Octabromophenylethyl‐Functionalized Cage Silsesquioxane and Its Use in Constructing Hybrid Porous Materials

Microporous Organic Polymers for Carbon Dioxide Capture

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