Targeted synthesis of a porous aromatic framework with a high adsorption capacity for organic molecules

Yuan, Ye; Sun, Fuxing; Ren, Hao; Jing, Xiaofei; Wang, Wei; Ma, Heping; Zhao, Huijun; Zhu, Guangshan

doi:10.1039/c1jm11998b

Cited by 154 publications

(103 citation statements)

References 43 publications

(49 reference statements)

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“…The tetrahedral, twist, and rigid structures of TPTCz ensure the growth of the 3D molecular network, high surface area, and uniform pore distribution. [23][24][25] The CMP fi lms were fabricated by multi cycle cyclic voltammetry (CV) in the potential range of -0.8 to 0.97 V (Scheme 1 a). From the second cycle in continuous CV scan, newly generated dimeric carbazole [19][20][21][22]26,27 ] redox peaks at the low potentials of 0.80 V (oxidation peak) and 0.71 V (reduction peak) were observed, and the peak current increased in successive cycles, indicating the coupling reaction between the carbazoles and the growth of the fi lm on the electrode.…”

Section: Doi: 101002/aenm201301771mentioning

confidence: 99%

Achieving High Efficiency of PTB7‐Based Polymer Solar Cells via Integrated Optimization of Both Anode and Cathode Interlayers

Chen

Zhang

et al. 2014

Advanced Energy Materials

104

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A poly(thieno[3,4‐b]‐thiophene/benzodithiophene) (PTB7)‐based polymer solar cell (PSC) with conventional structure can achieve a significant power conversion efficiency of 8.42%, which is realized by integrated optimization of both anode and cathode interlayers. The effects of a conjugated microporous polymer film as the anode interlayer are threefold: it enhances the contact with active layer, increases the work function and conductivity, and blocks electrons.

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Section: Doi: 101002/aenm201301771mentioning

confidence: 99%

Achieving High Efficiency of PTB7‐Based Polymer Solar Cells via Integrated Optimization of Both Anode and Cathode Interlayers

Chen

Zhang

et al. 2014

Advanced Energy Materials

104

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“…5.16b). Since then, various synthetic strategies have been used to synthesize CMPs, such as Yamamoto [132][133][134][135][136], Ullmann [137], Suzuki [138][139][140][141][142][143][144][145], Sonogashira-Hagihara coupling [146][147][148][149][150][151][152], oxidative coupling [145,153], and ethynyl cyclotrimerization [154][155][156]. As a result, the CMPs family was expanded quickly in the last several years.…”

Section: Conjugated Microporous Polymersmentioning

confidence: 98%

Microporous Organic Polymers for Carbon Dioxide Capture

Luo

Tan

2014

Green Chemistry and Sustainable Technology

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Microporous organic polymers (MOPs) are a unique class of porous materials consisting solely of the light elements (C, H, O, N, etc.). A series of vivid characteristics of MOPs, such as high-specific surface area, good physicochemical stability, diverse pore dimensions, topologies, and chemical functionalities, make them suitable adsorbents for CO 2 capture. In this chapter, MOPs are categorized into four classes according to the types of organic reactions and the chemical structures of the resulting materials: hypercrosslinked polymers (HCPs), covalent organic frameworks (COFs), polymers of intrinsic microporosity (PIMs), and conjugated microporous polymers (CMPs). For each type of the polymer network, the state-of-the-art development in the design, synthesis, characterization, and the CO 2 sorption performance is reviewed. Strategies for controlling CO 2 uptake capacity and adsorption enthalpy via manipulation of surface area, pore size, and functionality are discussed in detail. These studies would open up many new possibilities for the development of the novel solid sorbents targeting the CO 2 capture process. It is expected that this chapter will not only summarize the main research activities in this field, but also find possible links between basic studies and practical applications. Abbreviations ACMPAcetylene gas mediated conjugated microporous polymers BA Benzyl alcohol BC Benzyl chloride BCMA 9,10-Bis(chloromethyl)anthracene

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“…这种无定型结构可能是由于苯环之间的扭曲与穿插造成的. 相似的穿插结构在有机多孔材料中经常被观察到 [19,20] . 如图 5 所示, 在扫描电镜图片中我们可以看到该类材料为 1 μm 左右的球状颗粒, 透射电镜图片进一步证明该类材料为无定型物质.…”

Section: 电镜分析及粉末 X-ray 衍射分析unclassified

Designed Synthesis and Characterization of Novel Germanium Centered Porous Aromatic Frameworks (Ge-PAFs)

Yuan¹,

Yan²,

Ren³

et al. 2012

Acta Chim. Sinica

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Targeted synthesis of a porous aromatic framework with a high adsorption capacity for organic molecules

Cited by 154 publications

References 43 publications

Achieving High Efficiency of PTB7‐Based Polymer Solar Cells via Integrated Optimization of Both Anode and Cathode Interlayers

Achieving High Efficiency of PTB7‐Based Polymer Solar Cells via Integrated Optimization of Both Anode and Cathode Interlayers

Microporous Organic Polymers for Carbon Dioxide Capture

Designed Synthesis and Characterization of Novel Germanium Centered Porous Aromatic Frameworks (Ge-PAFs)

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