Tannic Acid Assisted Construction of Au-Ti Integrated Catalyst Regulating the Local Environment of Framework Ti toward Propylene Epoxidation under H2/O2
“…using XANES spectroscopy. 334 An-Au@TS-1 exhibits higher LIII edge intensity, indicating the loss of more d-electrons ( Figure 18 B). The An-Au@TS-1 composite catalyst can better interact with the titanium surface because of the presence of bridging oxygen.…”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… (B) Au LIII-edge XANES spectra of an-Au@TS-1 and un-Au@TS-1 (calibrated using Au foil standard sample). 334 Copyright 2023, Elsevier B.V. (C) Proposed structures of the Ti-IV(A), Ti-V (B) and Ti-VI (C) by DFT. 222 Copyright 2023, Published by Elsevier B.V.…”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… (B) Au LIII-edge XANES spectra of an-Au@TS-1 and un-Au@TS-1 (calibrated using Au foil standard sample). 334 Copyright 2023, Elsevier B.V. …”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… 353 , 354 Commonly used reactors also include stainless steel reactors, 76 , 111 , 222 quartz tubular reactor 5 , 228 , 226 , 355 and continuous flow fixed-bed reactor. 334 , 356 …”
“…using XANES spectroscopy. 334 An-Au@TS-1 exhibits higher LIII edge intensity, indicating the loss of more d-electrons ( Figure 18 B). The An-Au@TS-1 composite catalyst can better interact with the titanium surface because of the presence of bridging oxygen.…”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… (B) Au LIII-edge XANES spectra of an-Au@TS-1 and un-Au@TS-1 (calibrated using Au foil standard sample). 334 Copyright 2023, Elsevier B.V. (C) Proposed structures of the Ti-IV(A), Ti-V (B) and Ti-VI (C) by DFT. 222 Copyright 2023, Published by Elsevier B.V.…”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… (B) Au LIII-edge XANES spectra of an-Au@TS-1 and un-Au@TS-1 (calibrated using Au foil standard sample). 334 Copyright 2023, Elsevier B.V. …”
Section: Determination Of Active Sitesmentioning
confidence: 99%
“… 353 , 354 Commonly used reactors also include stainless steel reactors, 76 , 111 , 222 quartz tubular reactor 5 , 228 , 226 , 355 and continuous flow fixed-bed reactor. 334 , 356 …”
“…Thus, TA shows strong surface adhesion to versatile substrates. Moreover, TA can self-polymerize into a porous scaffold that can trap and coordinate metal ions via the phenolic groups; 14 however, related works using TA as dispersants or stabilizers for Pd/Al 2 O 3 have not been reported.…”
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