Tailor-made poly(vinylidene sulfide)s by Rh(I)–NHC catalyzed regioselective thiol-yne click polymerization

Nickel-Catalyzed Azide–Alkyne Click Polymerization toward 1,5-Regioregular Polytriazoles

“…Highly efficient polymerizations in a regio-/stereoselective manner under moderate conditions are always desired for the preparation of well-defined polymers. , One of the examples is the click polymerization, which enjoys remarkable features, such as atom economy, mild reaction conditions, high efficiency, regio-/stereoselectivity, and good functionality tolerance. , Over the past two decades, plentiful click polymerizations, including azide–alkyne, − Diels–Alder, − thiol–ene/yne, − hydroxyl-yne, − and amino-yne click polymerizations, − have been established and used for the construction of functional polymers.…”