The article uses data from the Shanghai and Shenzhen 300 Index and the Shenwanwan Industry Index from 2010 to 2021, constructs a dynamic weighted mixed Copula model based on GARCH EVT, analyzes the dependence between each industry and the market tail, and explores the systematic risk contribution of each industry based on marginal expected loss (MES). The empirical results indicate that industries such as agriculture, forestry, animal husbandry, and fishing, as well as non banking and finance, have relatively low tail dependence, while industries such as real estate and household appliances have relatively high tail dependence; The banking industry has the smallest contribution to systemic risk, while the construction materials industry has the largest contribution; During the 2015 "stock market crash", the tail dependence between industry indices such as real estate and mining and market indices increased, with the most significant increase in risk contribution from the defense, military, and chemical industries.