Unmanned aerial vehicle's (UAVs) small size, long-lasting battery, and flexible trajectory have produced widespread applications in radio communication systems, especially its usage as a cellular tower (gNB) for 5G services. At the same time, the mmWave's enormous available bandwidth makes it the primary contender for next-generation communication networks. This article aims to synthesize and assess the usage of mmWave concurrently in backhaul and access links for amplify-and-forward (AF) relay installed on the UAV. A mathematical framework is developed for the received power of the user equipment (UE) obtained in relay path (gNB-UAV-UE) and direct path (gNB-UE) via; (i) free space, and (ii) log-distance path loss model. The International Telecommunication Union recommended city model is used to assess the likelihood for LoS and NLoS paths in four urban environments; (i) high-rise urban, (ii) dense urban, (iii) urban, and (iv) suburban. Furthermore, various parameters, that is, UAV's position and amplification factor are stipulated to optimize the efficiency of a UAV-based AF relay for enhanced users coverage.