Synthetic Routes to Electroactive Organic Discotic Aromatic Triazatruxenes

Abstract

This paper gives a survey about the triazatruxene (triindole) particle, distinguishes its structure, and portrays a conceivable way to deal with its combination and structures of all at-present-known fluid precious stones in view of triazatruxene, in addition to checking its electronic element criticalness. Triazatruxene is a brilliant particle that has been uncovered in the recent 14 years as a discotic liquid crystal compound. Of late, this electron-rich particle turned out to be more alluring as a core center in the building of discotic liquid column with electro-dynamic properties that demonstrated a consistent hexagonal columnar mesophase under an expansive assortment of temperatures. Besides, numerous different properties in this delicate material brought a wide consideration up in organic electronic innovation devices, for example, light radiating diodes (organic light-emitting diode), field impact transistors (field-effect transistor), and photovoltaic cells. In this survey, triazatruxene and all particles closely resembling triazatruxene in the most recent 16 years until 2016 have been incorporated, including a brief summary of their applications in all fields, which will be introduced.

Chemistry and Properties of Indolocarbazoles

“…Finally, the triazatruxenes will not be discussed, as these systems have been reviewed recently. 36,37…”

“…As might be anticipated for a relatively unexplored compound class, there are relatively few publications concerning applications of indolo­[3,2- a ]­carbazoles, apart from the triazatruxenes, a group of extended star-shaped derivatives incorporating an additional indole unit fused to the central benzene ring. This particular topic has been treated recently in several reviews, ,, and it will therefore not be discussed in this account.…”

“…The chemistry and properties of extended heteroaromatic systems featuring for instance indolocarbazole cores have been discussed in depth in an excellent account and will therefore only be treated briefly in appropriate sections of the text when considered appropriate. Finally, the triazatruxenes will not be discussed, as these systems have been reviewed recently. , …”

From truxenes to heterotruxenes: playing with heteroatoms and the symmetry of molecules

“…This trend includes truxenes, as evidenced by numerous review papers. [1][2][3][4][5] The typical features of truxenes is their significant thermal and photostability. Truxenes and their heteroanalogues can be utilized in OLEDs, [6][7][8][9] OFETs, [10][11][12] DSSCs, [13][14][15] NLO, [16][17][18][19] sensors, 20,21 gases and small molecule storage [22][23][24] materials, and many more.…”

“…This trend includes truxenes, as evidenced by numerous review papers. [1][2][3][4][5] The typical features of truxenes is their significant thermal and a Institute of Organic Chemistry Polish Academy of Sciences, Kasprzaka 44/52 01-224 Warszawa, Poland. E-mail: kgorski@icho.edu.pl b Institute of Physical Chemistry Polish Academy of Sciences, Kasprzaka 44/52 01-224 Warszawa, Poland.…”