Synthetic Routes for Designing Furanic and Non Furanic Biobased Surfactants from 5‐Hydroxymethylfurfural

Abstract

This publication is part of a collection of invited contributions focusing on "Green Conversion of HMF". Please visit chemsuschem.org/collections to view all contributions.

Chemical transformations of 5-hydroxymethylfurfural into highly added value products: present and future

“…59 Pt/SiO 2 catalyst in neutral solution and Pt–ZrO 2 in acidic solution could efficiently oxidize HMF to DFF with high yield under aerobic conditions. 60 Taarning et al 61 reported that the oxidation of HMF over Au/TiO 2 catalyst in MeOH could produce dimethyl furan-2,5-dicarboxylate (DFD) in excellent yield at 130 °C under basic conditions. Skowronski et al 62 proposed that DFF could also be obtained through the electrochemical oxidation of HMF using biphasic H 2 O–CH 2 Cl 2 solvent in a divided cell equipped with a Pt anode.…”

Photocatalytic Transformation of Biomass and Biomass Derived Compounds—Application to Organic Synthesis

“…Thus, dehydration of pentoses or hemicellososes yields furfural while corresponding transformations of hexoses lead to hydroxymethylfurfural (HMF). These compounds are currently studied in connection with the production bulk products such as new polymers [ 194 , 197 ] or surfactants [ 198 , 199 , 200 ].…”

Synthesis of amine derivatives from furoin and furil over a Ru/Al2O3 catalyst

“…, furosemide). 3 The synthesis of furfurylamines can be conducted from FF and 5-hydroxymethylfurfural (HMF) by direct/reductive amination over homogeneous and heterogeneous catalysts. 4 Also, secondary and tertiary tetrahydrofurfurylamines can be accessed with high yield (>90%) from FF over Pd/Al 2 O 3 at room temperature and 1 bar H 2 .…”