Synthesis, Structures, and Reactivities of BCN-Heterocyclic B–N Chains
Chen Zhang,
Xin Jiang,
Yi Jing
et al.
Abstract:The BCN-heterocyclic B−N chain compounds, the sodium and potassium salts of 3 and 4 anions (Na3, Na4, and K4), were synthesized by reactions of ethane 1,2-diamineborane (BH 3 NH 2 CH 2 CH 2 NH 2 BH 3 , 1) and propane 1,2-diamineborane (BH 3 NH 2 CH 2 CH 2 CH 2 NH 2 BH 3 , 2) with MH (M = Na and K). Then, the neutral B−N chain compounds 5 and 6 were prepared with dehydrogenation of [NH 4 ]3 and [NH 4 ]4, formed by metathesis reactions of Na3 and Na4 with NH 4 Cl or NH 4 SCN, respectively. Compounds 7 and 8, ana… Show more
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