Synthesis, structures and optical properties of mononuclear La, Eu and Tb complexes supported by calix[4]arene ligands bearing three pendant salicylaldiminato arms
Lennart Günzel,
Martin Börner,
Berthold Kersting
Abstract:The synthesis and complexation behaviour of a new calix[4]arene ligand H4L3 bearing three pendant salicylaldimine arms towards selected lanthanide ions has been investigated. Reaction of H4L3 with Ln(NO3)3⋅6H2O in MeOH in the presence of NEt3 provides monomeric complexes of composition [Ln(HL3)] (Ln=La3+ (4), Eu3+ (5), Tb3+ (6)). An X‐ray crystallographic analysis for 4 reveals that only two of the three ligand arms are involved in the coordination of the lanthanide ions, to give eight‐coordinated Ln3+ ions in… Show more
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