Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid

Dai, Hai-Yu; Wang, Cuijuan; Tang, Yixin; Yan, Tong; Mao, Kangshan; Zhang, Zhibin; Zhou, Xian‐Li

doi:10.1007/s10904-016-0446-z

Cited by 5 publications

(1 citation statement)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Coordination polymers(CPs) have attracted intense interest for their structural diversity and potential applications in many areas, such as gas adsorption/separation [1][2][3], catalysis [4], luminescence sensing [5,6], battery [7][8][9], supercapacitor [10,11], and magnetism [12,13]. The design and selection of organic ligands and metal ions are critical factors for the construction of CPs, due to the coordination mode of organic ligands and functional groups in them are directly affect the configuration and applications of the CPs.…”

Section: Introductionmentioning

confidence: 99%

High Efficiency Electrochemiluminescence for Copper(II) and Cadmium(II) Pyrazolate Polymers

Hua

Feng

Xie

et al. 2021

J Inorg Organomet Polym

View full text Add to dashboard Cite

Two new coordination polymers, namely, [Cu2(L)2(4,4′-bpy)]n (1) and [Cd(HL)Cl(1,10′-phen)]n (2) (H2L = 1H-pyrazole-3-carboxylic acid, 4,4′-bpy = 4,4′-bipyridine, 1,10′-phen = 1,10-phenanthroline) have been synthesized via solvothermal method and were structurally characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis and PXRD.The two complexes are both infinite 1D chain structures, in complex 1 the H2L ligands are completely deprotonated and chelating the metal centers, while in complex 2, H2L ligands play a role in chelating-bridging the metal centers. What's more, the two complexes further extended to 3D supramolecular networks by hydrogen bonds and weak C-H⋯π interactions. The weak intermolecular interactions existed in the complexes structures were further studied by Hirshfeld surface analysis and 2D fingerprint plots. In addition, these two transition mental complexes exhibit high intense electrochemiluminescence (ECL) in N,N-dimethylformamide (DMF) and after ten circulations the ECL intensity still remains stable, which can be a useful guide for the construct of new polymers ECL materials.

show abstract