Synthesis, Structure and Reactivity of Stable Homoleptic Gold(I) Alkene Cations

Abstract

The rate of absorption of hydrogen, argon, and xenon into a Type II propane clathrate hydrate has been studied. The propane hydrate is synthesized from 250‐μm ice grains, is estimated to have a porosity of 65% and has roughly the consistency of chalk. Hydrogen is rapidly absorbed by the hydrate sample and approaches the equilibrium vapor pressure in an hour before a very slow residual absorption process ensues. For an initial hydrogen pressure of 1.5 MPa, about 4.5% of the available 512 cages are occupied by hydrogen after 1 h, and 4.9% after 18 h. In contrast, for both argon and xenon significantly more gas is absorbed by the hydrate but at a much slower rate: about 5% as fast for xenon and 1% as fast for argon. We conclude that hydrogen readily diffuses through the propane hydrate microcrystal structure, while argon and xenon are probably absorbed by growing new double hydrate while consuming the propane hydrate. Although considerably higher pressures would be required to store significant quantities of hydrogen in propane hydrate, it appears that the crystal can be loaded and emptied in relatively short times. © 2010 American Institute of Chemical Engineers AIChE J, 2010

Auriferous alkynylselenolatoalkylidynes

“…18 The alkynylselenolatoalkylidynes 2a-2i were prepared as reported previously. 2a The complexes [AuCl(THT)], 21 [AuCl(SMe2)] 22 and [AuCl(PPh3)] 23 were prepared according to literature methods. [AuCl(PCy3)] was prepared by the reaction of an equimolar amount of [AuCl(THT)] and PCy3.…”

Structural, Electrochemical, and Photochemical Properties of Mono‐ and Digold(I) Complexes Containing Mesoionic Carbenes

“…General Procedures, Materials, and Instrumentation: AuCl(SMe 2 ), [ L1 ]I/BF 4 , [ L2 ](BF 4 ) 2 ,[2g], and 1 were prepared as described previously in the literature. Commercially available chemicals were used as purchased, unless otherwise noted.…”

Metal–Arene Interactions in Dialkylbiarylphosphane Complexes of Copper, Silver, and Gold

“…[76] The same holds true for gold analogues 4 a-d, in which the Au I ÀC distances d are very similar to those found in alkene-gold(I) complexes. [54,55,77,78] Conclusion Gold(I) interacts weakly with the covering arene ring in complexes with dialkylbiphenylphosphane ligands. Thus, in 6 a the gold-arene distance (3.04 ) is longer than the maximum estimated for a meaningful metal-arene interaction (2.95 ).…”