Abstract:Main observation and conclusion
We report the design, synthesis, structure, and properties of two complex layered phosphide nitrides, AkTh2Mn4P4N2 (Ak = Rb, Cs), which contain anti‐fluorite‐type [Mn2P2] bilayers separated by fluorite‐type [Th2N2] layers as a result of the intergrowth between AkMn2P2 and ThMnPN. The new compounds are featured with an intrinsic hole doping associated with the interlayer charge transfer and a built‐in chemical pressure from the [Th2N2] layers, both of which are reflected by the c… Show more
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