Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes

Enthalpy of formation of 6-phenyl-1,5-diazabicyclo[3.1.0]hexane by combustion calorimetry and theoretical approach for efficient prediction of thermochemistry of diaziridines

“…15,[17][18][19][20] Available experimental data allowed for a better understanding of the conformational behavior of DABHs in the gaseous and crystalline phases. 20 Due to its high enthalpy of formation and low toxicity, DABH was found to be a promising liquid propellant as an alternative to toxic hydrazine derivatives. 21,22 The possibility of using solid PDABH as a high-energy material is yet to be explored and, therefore, the thermochemical properties of DABHs and other diaziridine derivatives are critical to the successful modeling of diaziridine-based high-energy materials.…”

“…X-ray diffraction studies were performed on PDABH 17 and other derivatives of DABH. 15,17–20 Available experimental data allowed for a better understanding of the conformational behavior of DABHs in the gaseous and crystalline phases. 20…”

“…15,17–20 Available experimental data allowed for a better understanding of the conformational behavior of DABHs in the gaseous and crystalline phases. 20…”

“…X-ray diffraction studies were performed on PDABH 17 and other derivatives of DABH. 15,[17][18][19][20] Available experimental data allowed for a better understanding of the conformational behavior of DABHs in the gaseous and crystalline phases. 20 Due to its high enthalpy of formation and low toxicity, DABH was found to be a promising liquid propellant as an alternative to toxic hydrazine derivatives.…”