Synthesis, structure and luminescence properties of the europium–containing NASICON type phosphates

Asabina, E. A.; Sedov, Vladislav; Петьков, В. И.; Deyneko, Dina V.; Kovalsky, A. M.

doi:10.1007/s10971-022-06028-z

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2023

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“…The structure of these double phosphates includes a metal-phosphate three-dimensional framework and is characterized by high thermal and chemical stability. Their structural features provide the ability for ion exchange and prospects for their application as matrices for radioactive elements immobilization [3][4][5][6], as well as for design of luminescent materials [7][8][9].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and thermal behavior of KCe2(PO4)3, a new full-member in the AIMIV 2 (PO4)3 family

Kozlova¹,

Vasilyeva²,

Козлов³

et al. 2023

Nanosystems: Phys. Chem. Math.

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Hydrothermal treatment of nanoscale amorphous ceric phosphate gel in KOH aqueous solutions was found to result in a new KCe 2 (PO 4 ) 3 phase. The refinement of the KCe 2 (PO 4 ) 3 structure showed that it was isostructural to recently reported (NH 4 )Ce 2 (PO 4 ) 3 . For the KCe 2 (PO 4 ) 3 phase, the unit cell parameters (sp. gr. C2/c) were a = 17.3781(3) Å, b = 6.7287(1) Å, c = 7.9711(2) Å, β = 102.351(1) • , V = 910.53(4) Å3 , Z = 4. The thermal decomposition of KCe 2 (PO 4 ) 3 at 800 • C resulted in the mixture of crystalline CePO 4 and KPO 3 .

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