Synthesis, structure, and heterogeneous Fenton reaction of new Cu(ii)-based discrete Cu₂L_x coordination complexes

Abstract

Discrete and polymeric coordination complexes [Cu2L4(ClO4)4]·2CH2Cl2·CH3OH (1), [Cu2L2(NO3)4(CH3OH)2] (2) and {[Cu2L4(NO3)4]}n (3) were obtained by using bridged pyridine ligand 4-methyl-2,6-bis(pyridinyl-3-ethynyl) aniline (L) and Cu(II) salts in CH2Cl2/MeOH. The structure of...

Synthesis, characterization and anticancer activities of Zn2+, Cu2+, Co2+ and Ni2+ complexes involving chiral amino alcohols

“…Recently, amino alcohols involved coordination compounds with the rst transitional metal such as Co 2+ , Cu 2+ and Zn 2+ and have already been studied because of their good anticancer activities and low toxicity. [22][23][24] What' more, amino alcohol complexes can also play a key role in catalysis one hand and become a vital aspect of human life on the other hand. Most of the rst-transition metal such as cobalt, copper and zinc complexes are all also very essential for living organisms.…”