Synthesis, structure, and characterization of a mixed-valence manganese(III)-manganese(IV) bis(.mu.-oxo) complex with a macrocyclic tetraaza ligand

Synthesis, Structure, Electronic, Redox, and Magnetic Properties of a New Mixed-Valent Mn-Oxo Cluster: [Mn2III,IVO2(N,Nbispicen)2]3+ (N,Nbispicen =N,N-bis(2-pyridylmethyl)-1,2-diaminoethane)

“…The modifications described above are reversible by varying the potential applied appropriately. The observations reported above are very similar to those made by Brewer et al [27] …”

Electrooxidation of Fe, Co, Ni and Cu Metalloporphyrins on Edge‐Plane Pyrolytic Graphite Electrodes and Their Electrocatalytic Ability towards the Reduction of Molecular Oxygen in Acidic Media

“…Spectroelectrochemical measurements were conducted according to a previously described method by using a locally constructed Hcell, which uses a quartz cuvette as the working compartment. [32] The working and auxiliary compartments were separated by a fine porous-glass frit. The working electrode was a high-surface-area platinum mesh, and the auxiliary electrode was a platinum wire.…”

Mechanistic disparity in the electron transfer reactions of thiosulfate with di‐μ‐oxo‐bis(1,4,8,11‐tetraazacyclotetradecane)‐dimanganese(III,IV) and di‐μ‐oxo‐bis(1,4,7,10‐tetraazacyclododecane)‐dimanganese(III,IV) complexes

“…The complex 1 was also synthesized according to the literature procedure [10,11] and characterized by the elemental analysis and UV-Vis spectroscopy [10,12]. Anal.…”

“…It was synthesized by modifying the procedure reported previously [10]. The modified procedure gives the complex 2 in purer form and also reduces the reaction time significantly.…”