Synthesis, Structural Versatility, Magnetic Properties, and I− Adsorption in a Series of Cobalt(II) Metal–Organic Frameworks with a Charge-Neutral Aliphatic (O,O)-Donor Bridge
Ksenia D. Abasheeva,
Pavel A. Demakov,
Evgeniya V. Polyakova
et al.
Abstract:Four new metal–organic frameworks based on cobalt(II) salts and 1,4-diazabicyclo[2.2.2]octane N,N’-dioxide (odabco) were obtained. Their crystallographic formulae are [Co3(odabco)2(OAc)6] (1, OAc− = acetate), [Co(H2O)2(HCOO)2]·odabco (2), [Co2(H2O)(NO3)(odabco)5](NO3)3·3.65H2O (3), and [Co2(DMF)2(odabco)4](NO3)4·3H2O (4; DMF = N,N-dimethylformamide). Crystal structures of 1–4 were determined by single-crystal X-ray crystallography. Coordination polymer 1 comprises binuclear and mononuclear metal–acetate blocks… Show more
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