Synthesis, structural peculiarities, and photosensitivity of fluorinated dibenzo-1,2,5,6-tetrathiocines

Abstract

Synthesized fluorinated dibenzo-1,2,5,6-tetrathiocines are structurally flexible in the solid state (XRD), solution (NMR, NOESY), and gas phase (DFT). In solution under sunlight, they isomerize in rare dibenzo-1,2,3,6-tetrathiocines (XRD).