Synthesis, structural, optical, and dielectric properties of novel barium-doped bismuth selenide

Batool, Zahida; Bashir, Sana; Ismail, Muhammad; Kousar, Rehana; Manzoor, Muhammad Zeewaqar; Khan, Hassan; Kalsoom, Ambreen

doi:10.1007/s10854-022-08598-8

Cited by 5 publications

(1 citation statement)

References 29 publications

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“…The A g and T g bands are near 225 cm −1 and 248 cm −1 , pointing to the existence of RuSe 2 [42]. Additionally, it can be seen from figure 2(c), the peaks at 3420 cm −1 , 2970 cm −1 and 1050 cm −1 for RuSe 2 /CeO While the peaks at 1630 cm −1 for RuSe 2 /CeO 2 points to C=O allocated to CO 2 from the air environment [45]. The peaks at 720 cm −1 for RuSe 2 /CeO 2 and RuSe 2 correspond to the stretching vibration of metal-Se bond, which indicates the existence of Ru-Se bond [46].…”

Section: Physical Characterizationsmentioning

confidence: 78%

RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

Li,

Huo,

Dong

et al. 2023

Nanotechnology

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Constructing heterojunction to adjust the electronic structure of catalysts is a promising strategy for synergistically improving electrocatalytic activity. In addition, RuSe2 is recognized as an effective alternative to Pt for boosting alkaline hydrogen evolution reaction (HER) on account of its outstanding catalytic properties. Herein, novel RuSe2/CeO2 heterojunction electrocatalysts are fabricated through hydrothermal and thermal treatment methods. The optimal 50% RuSe2/CeO2 heterojunction electrocatalyst exhibits a low HER overpotential of 16 mV to attain 10 mA cm−2 current density and Tafel slope of 66.1 mV dec−1 for hydrogen evolution in 1.0 M KOH. At the same time, the 50% RuSe2/CeO2 heterojunction electrocatalyst also maintains a stable HER activity for 50 h or 3000 CV cycles. The experimental results show that formation of heterogeneous interface between RuSe2 and CeO2 results in the redistribution of electrons at the RuSe2/CeO2 interface, thereby changing the electronic structure of RuSe2 and enhancing the performance of the RuSe2/CeO2 electrocatalyst. This work may provide a feasible way to design efficient hydrogen evolution heterojunction electrocatalysts by modulating the electronic structure in alkaline electrolytes.

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Section: Physical Characterizationsmentioning

confidence: 78%

RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

Li,

Huo,

Dong

et al. 2023

Nanotechnology

View full text Add to dashboard Cite

show abstract

Synergistic activation of lamellar bismuth selenide anchored functionalized carbon nanofiber for detecting hazardous carbendazim in environmental water samples

Jayapaul,

Lin,

Lin

et al. 2024

Chemosphere

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In vivo toxicity evaluation and antibacterial assessment of vanadium doped Bi2Se3 synthesized by cost effective method

Musarrat,

Fatima,

Batool

et al. 2024

Materials Chemistry and Physics

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Synthesis, structural, optical, and dielectric properties of novel barium-doped bismuth selenide

Cited by 5 publications

References 29 publications

RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

Synergistic activation of lamellar bismuth selenide anchored functionalized carbon nanofiber for detecting hazardous carbendazim in environmental water samples

In vivo toxicity evaluation and antibacterial assessment of vanadium doped Bi2Se3 synthesized by cost effective method

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Synthesis, structural, optical, and dielectric properties of novel barium-doped bismuth selenide

Cited by 5 publications

References 29 publications

RuSe2/CeO2 heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

RuSe2/CeO2 heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

Synergistic activation of lamellar bismuth selenide anchored functionalized carbon nanofiber for detecting hazardous carbendazim in environmental water samples

In vivo toxicity evaluation and antibacterial assessment of vanadium doped Bi2Se3 synthesized by cost effective method

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Resources

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RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution

RuSe₂/CeO₂ heterostructure as a novel electrocatalyst for highly efficient alkaline hydrogen evolution