Synthesis, structural characterization, catalytic activity on aerobic oxidation of novel Co(II) and Fe(II) phthalocyanines and computational studies of 4-[2-(2,3-dichlorophenoxy)ethoxy]phthalonitrile

Çinko(II)–Sulfatiyazol-Dietilentriamin Kompleksinin Hesaplamalı Kimya Yöntemi ile Spektroskopik Özelliklerinin İncelenmesi: Moleküler Modelleme Çalışması

“…MEP, moleküllerin elektrofillik veya nükleofillik reaktif bölgelerini görselleştirmek ve renk kodları ile elektrostatik potansiyel bölgeleri göstermek için kullanılır (Dani et al 2013, Saka et al 2016. Kompleksin moleküler elektrostatik potansiyelinin 3D grafikleri Şekil 9' da gösterilmiştir.…”

Kinetic study of α-pinene allylic oxidation over FePcCl16-NH2-SiO2 catalyst

“…The UV-vis band near to 630 nm confirms the presence of µ-oxo dimeric species [29,34]. The region between 600-800 nm is referred as the Q band correspond to the π -π* transition from the HOMO (highest occupied molecular orbital) to the LUMO (lowest unoccupied molecular orbital) of the Pc -2 ring, the broad band in the 300-400 nm region consists of more than one component, and is referred to as the Soret region or B band with deeper π -π* transitions [35]. The three-bands in the 200-300 nm region, which are referred to as N, L, and C bands in order of increasing energy, are together with the B bands, sensitive to the central metal.…”

Recent Advances in the Use of CoPc-MWCNTs Nanocomposites as Electrochemical Sensing Materials

“…The high catalytic activity of metal phthalocyanine is attributed to the central metal ions [ 6 , 27 ]. Among these MPcs, cobalt phthalocyanine (CoPc) is one of the bright catalysts for varied organic reactions because of its high activity and selectivity of oxidation processes [ 6 , 28 , 29 , 30 ]. CoPc has been widely used as a mediator in electronic devices and in constructing electrochemical sensors due to its electronic, catalytic, and semi-conductor proprieties; besides, it can be anchored in cationic substrates by simple adsorption processes [ 31 , 32 ].…”