Synthesis, spectroscopic study and carbofuran adsorption of mixed metal (Co, Cu)@Ca-BTC frameworks aimed at wastewater cleaning

Emam, Hossam E.; Koto, Teruaki; Sebok-Nagy, Krisztina; El-Shahat, Mahmoud; Abdel-Gawad, Hassan; Pali, Tibor; Abdelhameed, Reda M.

doi:10.1016/j.jiec.2024.05.019

Cited by 4 publications

(1 citation statement)

References 81 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Recently, a porous crystalline material with good thermal stability known as Metal–Organic Frameworks (MOFs) was created by bridging the coordination of metal and organic groups while adding inorganic nodes 43 – 46 . Due to their regulated morphology and stable structure 47 – 56 , MOFs have attracted particular attention from researchers for their effectiveness in photocatalysis 57 – 69 ; Ce-BTC is one of the most efficient catalysts 70 . Cerium, on the other hand, has two main oxidation states because it is a member of the lanthanide family.…”

Section: Introductionmentioning

confidence: 99%

Urea production via photocatalytic coupling of mixed gases (CO2/NH3) using Mo(MnO4)5 supported on Ce-BTC as nano-composite catalyst

El-Shahat,

Abdelhameed

2024

Sci Rep

View full text Add to dashboard Cite

Urea used in fertilization and feed supplement, as well as a starting material for the manufacture of plastics and drugs. Urea is most commonly produced by reacting carbon dioxide with ammonia at high temperature. Photocatalysis has gained attention as a sustainable pathway for performing urea. This work focus on designing very active photocatalysts based on cerium organic framework (Ce-BTC) doped with metal oxide nanoparticles (molybdenum permanganate, Mo(MnO4)5) for production of urea from coupling of ammonia with carbon dioxide. The prepared materials were characterized using different spectral analysis and the morphology was analysed using microscopic data. The effect of catalyst loading on the production rate of urea was investigated and the obtained results showed speed rate of urea production with high production yield at low temperature. The recyclability tests confirmed the sustainability of the prepared photocatlysts (Mo(MnO4)5@Ce-BTC) which supported the beneficial of the photocatalysis process in urea production.

show abstract