Synthesis, spectroscopic studies and crystal structure of cadmium nitrosylpentacyanomanganate (I) pentadecahydrate

A New Family of Bimetallic Framework Materials Showing Reversible Structural Transformations

“…The environment of the topological nodes is shown in Figure S6 The RusC and C-N bond distances and CsRusC angles are in good agreement with published values. [61][62][63][64] The Cu II ion is penta-coordinated, bonding to two nitrogen atoms of two equivalent tn ligands (N4, N5), and to three nitrogen atoms of the cyano groups (N1, N2 and N3). The NsCusN angles in the pseudo base deviate strongly from ideal trigonal-bipyramidal geometry ( Figure 6).…”

Sponge-like Reversible Transformation of a Bimetallic Cyanometallate Polymer

“…Four of the six CNgroups are nonbridging, while the other two bond to the Cu atoms giving rise to Ru-CtN-Cu bridges. 36,38,39 TG and DSC Analysis. The thermal stability of 1 has been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC).…”

The first heterobimetallic one dimensional cyano bridged nitrosyl complex containing an alkaline earth metal: synthesis, characterization and crystal structure of the complex [Sr(Phen)2(DMF)2][Fe(NO)(CN)5]

“…To our knowledge this class of nitrosyl complex is reported for the first time and the incorporation of strontium is to ensure the minimal toxicity of the bimetallic complex so as to keep the provision of using the compound in biological system. Besides the biological interest the study of pentacyanonitrosyl metalates of transition metal elements has also received remarkable attention in recent years [5][6][7][8] due to their important roles as molecular sieves, electron scavengers, cation exchangers and radionuclide sorbents [9,10].Title compound was synthesized by mixing an aqueous solution (10 ml) of Na 2 [Fe(CN) 5 NO] AE 2H 2 O (0.30 g; 1.0 mmol) to a 10 ml aqueous solution of SrCl 2 AE 6H 2 O (0.54 g; 2.0 mmol) and adding the resulting solution to 10 ml of methanolic solution of 1,10 phenanthroline monohydrate (0.79 g; 4.0 mmol). The precipitate obtained was then crystallized from DMF.…”

“…Besides the biological interest the study of pentacyanonitrosyl metalates of transition metal elements has also received remarkable attention in recent years 1387-7003/$ -see front matter Ó 2004 Elsevier B.V. All rights reserved. doi:10.1016/j.inoche.2004.08.005 [5][6][7][8] due to their important roles as molecular sieves, electron scavengers, cation exchangers and radionuclide sorbents [9,10].…”

“…To our knowledge this class of nitrosyl complex is reported for the first time and the incorporation of strontium is to ensure the minimal toxicity of the bimetallic complex so as to keep the provision of using the compound in biological system. Besides the biological interest the study of pentacyanonitrosyl metalates of transition metal elements has also received remarkable attention in recent years [5][6][7][8] due to their important roles as molecular sieves, electron scavengers, cation exchangers and radionuclide sorbents [9,10].…”