Synthesis, Spectroscopic Investigations, Thermal Analysis And DFT Calculations Of Some Pentacarbonyl(Mercaptopyrimidine)Metal(0) Complexes Of Group VI B Elements
Abstract:Pentacarbonyl-N-mercaptopyrimidinemetal(0) complexes of VIB metals (M: Cr, Mo, W) were formed when hexacarbonylmetal(0) complexes are treated photochemically with 4,6-dimethyl-2-mercaptopyrimidine at 10 ºC. The reported organometallic complexes were purified and isolated under an inert atmosphere. All M(CO)5L complexes were characterized in solution by FTIR-, 1H- and 13C-NMR spectroscopies. The FTIR spectroscopy results showed three absorption bands in the carbonyl region which indicates that the pentacarbonyl… Show more
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