Synthesis, spectroscopic, in vitro, in silico, and in vivo studies of binuclear Cu (II), Ni (II), Ru (II), and Zn (II) complexes with tetradentate Schiff base ligand
Abstract:A novel Schiff base macrocyclic ligand was synthesized by the condensation of 4-(3,4-diaminophenyl)benzene-1,2-diamine with β-naphthol-1-aldehyde.Binuclear complexes were synthesized from this Schiff base by reaction with Cu (II), Ni (II), Ru (II), and Zn (II) metal salts. Square planar geometrical structures of Cu (II), Ni (II), and Ru (II) complexes were achieved by several physicochemical methods, namely UV-Vis, FT-IR, NMR, ESI-Mass, and thermogravimetric analysis, respectively. Density functional theory (D… Show more
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