Synthesis, spectral characterization, and electrochemical property of Cu(II) complex with 1,2-phenylenedioxydiacetic acid and 1,10-phenanthroline

Synthesis, Structural Characterization and Electrochemical Property of a Dinuclear Cu (II) Complex Material

“…(5) shows the topological structure of the Cu (II) complex. The structure of Cu (II) is different from that of the Cu(II) complex reported previously [14], indicating that the same ligand and metal ion can form different structure when the synthetic condition was changed. As shown in Figs.…”

“…The electrochemical behavior of the Cu (II) complex was determined, and the process of measurement is the same with those reported previously [14]. As shown in Fig.…”

“…Both carboxylates and phen are good organic ligand because they not only have rich coordination points and strong coordination ability but can also construct the molecular structure of multiple structures [11][12][13]. We have synthesized a novel dinuclear Cu(II) complex by the selfassembly of 1, 2-phenylenedioxydiacetic acid, 1,10phenantroline (phen) and Cu(CH 3 COO) 2 •H 2 O in the presence of MgCl 2 [14]. For comparison, we synthesized and reported herein another novel dinuclear Cu(II) complex, based on 1, 2-phenylenedioxydiacetic acid and phen ligands without the presence of MgCl 2 .…”