Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: the crystal structure of Zn(234-MeO-Ba)2En)I2

Khalaji, Aliakbar Dehno; Akerdi, S. Jalali; Grivani, Gholamhossein; Stœckli-Evans, Helen

doi:10.1134/s1070328411080045

Cited by 5 publications

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“…For related structures, see: Khalaj et al (2008Khalaj et al ( , 2009; Salehzadeh et al (2011); Khalaji et al (2010Khalaji et al ( , 2011Khalaji et al ( , 2012. For properties and application of complexes of symmetric bidentate Schiff base ligands, see: Komatsu et al (2007); Montazerozohori et al (2011).…”

Section: Related Literaturementioning

confidence: 99%

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[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc

et al. 2012

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In the title compound, [ZnBr 2 (C 17 H 14 Cl 4 N 2 )], the Zn II ion is bonded to two bromide ions and two N atoms of the diimine ligand and displays a moderately distorted tetrahedral coordination geometry. The Schiff base ligand acts as a chelating ligand and coordinates to the Zn II atom via two N atoms.

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Section: Related Literaturementioning

confidence: 99%

“…(Komatsu et al, 2007) and thermal properties (Montazerozohori et al, 2011). There is substantial interest in the coordination chemistry of the zinc(II) ion (Khalaj et al, 2008(Khalaj et al, , 2009Salehzadeh et al,2011;Khalaji et al,2010Khalaji et al, , 2011Khalaji et al, , 2012.…”

Section: Data Collectionmentioning

confidence: 99%

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc

et al. 2012

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Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O

Basdouri

Trojette

Falvello

et al. 2019

Journal of Molecular Structure

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Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O. AbstractThe new organic-inorganic hybrid material [Zn(H2O)6][{(CH2)6N4}ZnCl3]2·0.5 H2O, is the second hydrate in this system, the first having been the hexahydrate. The new solid was prepared by slow evaporation of a solution of the reactants at room temperature and was structurally characterized by X-ray crystallography. This compound crystallizes in the trigonal system, space group P-3c1 with a = 9.8303(2)Å, c = 17.5460(2)Å, V = 1468.38(4)Å 3 and with Z = 2. The complex was characterized by FT-IR, thermogravimetric analysis (TGA), differential thermal analysis (DTA) and with a detailed analysis of Hirshfeld surfaces and fingerprint plots. The structural unit of the title compound consists of a [Zn II (H2O)6] 2+ cation, two [Zn II Cl3(hmt)]anions and half of a water molecule, partially occupied and disordered [hmt is hexamethylenetetramine, (CH2)6N4]. Crystal packing is mediated by O-H…N and O-H…Cl hydrogen bonds between the anions and cations, and to a lesser extent by O-H…O contacts, which are present only part of the time as a consequence of the partial occupancy of the isolated water molecules. The relationship between the packing in the new structure and that of the previous hexahydrate is described.

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Zinc(II) and mercury(II) complexes [Zn((2,6-Cl-ba)2en)I2] and [Hg((2,6-Cl-ba)2en)Br2] with the bidentate Schiff base ligand (2,6-Cl-ba)2en: Synthesis, characterization and crystal structures

et al. 2013

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Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: the crystal structure of Zn(234-MeO-Ba)2En)I2

Cited by 5 publications

References 12 publications

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc

Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O

Zinc(II) and mercury(II) complexes [Zn((2,6-Cl-ba)2en)I2] and [Hg((2,6-Cl-ba)2en)Br2] with the bidentate Schiff base ligand (2,6-Cl-ba)2en: Synthesis, characterization and crystal structures

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Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: the crystal structure of Zn(234-MeO-Ba)2En)I2

Cited by 5 publications

References 12 publications

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ2N,N′]dibromidozinc

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ2N,N′]dibromidozinc

Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O

Zinc(II) and mercury(II) complexes [Zn((2,6-Cl-ba)2en)I2] and [Hg((2,6-Cl-ba)2en)Br2] with the bidentate Schiff base ligand (2,6-Cl-ba)2en: Synthesis, characterization and crystal structures

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[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ²N,N′]dibromidozinc