Synthesis, physical properties and enzymatic degradation of bio-based poly(butylene adipate-co-butylene furandicarboxylate) copolyesters

Zhou, Weidong; Wang, Xiaowei; Yang, Bing; Xu, Ying; Zhang, Wei; Zhang, Yajie; Ji, Junhui

doi:10.1016/j.polymdegradstab.2013.08.025

Cited by 106 publications

(62 citation statements)

References 32 publications

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“…96,98 This same tendency was also observed for PBA-co-PBF copolyesters. 95,97 As expected, the thermal properties of the corresponding copolyesters were also affected by their crystalline structures (Table 2). In the case of PBF-co-PBS copolyesters, when BF content was lower than 10 mol%, T m values were c.a.…”

Section: Methodssupporting

confidence: 72%

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

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Motivated by a general concern on sustainability and environmental issues, a sparkling search for renewable-based polymers has grown exponentially in recent years. This search definitely spotlighted polyesters derived from 2,5-furandicarboxylic acid, among other polymers, as some of the most promising, especially due to the resemblance of this renewable monomer to the well-known petroleum-based terephthalic acid, as well as for the possibility of preparing innovative materials. The huge number of recent papers and patents about this family of polymers explore aspects such diverse as synthesis with other renewable-based monomers, leading to the preparation of materials with enhanced thermo-mechanical, biodegradability and liquid crystalline properties, among other features. Additional aspects pursued in such studies are innovation in the synthetic approaches or its optimisation; and also the development of applications for everyday-life objects like for example packaging materials, especially bottles, textiles, coating, toners, among many other uses. Despite this intense activity little has been reviewed recently about this unique family of polyesters, or derived polymers, as the only reviews on the subject date-back from the last century. In this perspective, the present appraisal aims at contributing to fulfil this literature gap, covering recent aspects related with challenges of developing polyesters, polyamides, or other polymers from 2,5-furandicarboxylic acid and their precursors. Emphasis is placed on monomer synthesis, polymerisation reactions, catalysts and applications.A tribute to 2,5-furandicarboxylic acid excellency and the myriad of novel polyesters, but also polyamides, among other polycondensates, is comprehensively done.

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Section: Methodssupporting

confidence: 72%

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

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“…Similar results were obtained in our previous work with aliphatic-aromatic copolymers 61 , as also by other researchers 82,85 . In the case of furanoate copolymers it was found that copolymerization of PEF with lactic acid enhanced its hydrolysis rate 86,87 , as also the presence of butylene adipate in poly(butylene furanoate) polyester resulted in accelerated hydrolysis by lipase 88 . This behavior is attributed to the higher hydrophobicity of the furanoate units and the increased rigidity they provide, therefore less mobility of the macromolecular chains.…”

Section: Enzymatic Hydrolysismentioning

confidence: 99%

Biobased poly(ethylene furanoate-co-ethylene succinate) copolyesters: solid state structure, melting point depression and biodegradability

et al. 2016

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Poly(ethylene furanoate) (PEF) is a fully bio-based polyester with unique gas barrier properties, considered an alternative to poly(ethylene terephthalate) (PET) in food packaging applications. However, it is not biodegradable. For this reason copolymerization with the aliphatic succinic acid monomer, was followed. The respective poly(ethylene furanoate-co-ethylene succinate) (PEFSu) copolymers were prepared via melt polycondensation from 2,5-dimethylfuran-dicarboxylate, succinic acid and ethylene glycol at different ratios.1 HNMR spectroscopy showed the copolymers are random. The crystallization and melting of the copolymers were thoroughly evaluated. Isodimorphic cocrystallization was concluded from both the 2 WAXD patterns and the minimum in the plots of melting temperature versus composition. The pseudo-eutectic melting point corresponded to an ethylene succinate content of about 30 mol%. The enzymatic hydrolysis tests using of Rhizopus delemarand Pseudomonas Cepacia lipase, revealed that the copolymers with up to 50 mol% ES units show measurable weight loss rates. For higher ES content, the copolymers showed fast hydrolysis.

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“…PBF material has largely reduced carbon dioxide permeability (19×) and diffusivity (31×) compared to the respective properties of PET [9]. Other polyesters like poly(butylene 2,5-furandicarboxylate) (PBF) [10], poly(butylene adipate-co-butylene 2,5-furandicarboxylate) (PBAF) [11] and poly(butylene succinic-co-butylene 2,5-furandicarboxlylate) (PBSF) [12] with satisfying thermomechanical properties were also successfully prepared. PBF has high tendency to crystallize and allows the continuous fibers to be drawn from melt.…”

Section: Introductionmentioning

confidence: 99%

Poly(butylene 2,5-furandicarboxylate-ε-caprolactone): A new bio-based elastomer with high strength and biodegradability

Zheng¹,

Zang²,

Wang³

et al. 2017

Express Polym. Lett.

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Abstract.A new bio-based elastomer, poly(butylene 2,5-furandicarboxylate-ε-caprolactone) (PBFCL), has been synthesized from 2,5-furandicarboxylic acid, 1,4-butanediol, and ε-caprolactone successfully for the first time. The obtained copolyester was characterized in terms of chemical structure, thermal and mechanical properties, and enzymatic degradability. In PBFCL elastomer, butylene-2,5-furandiacrboxylate units (hard segments) crystallize to serve as physical crosslinks while ε-caprolactone polyester diol (soft segments) provide flexibility. PBFCL is a multi-blocked copolyester with randomly distributed rigid and soft segments. It possesses original feature of high strength and biodegradability stemming from the uses of aromatic and aliphatic monomers respectively. An important aspect of this new furanic-aliphatic polyester is its tailor-made properties simply achieved by changing the content of hard or soft segments. Typically, PBFCL-40 of optimal composition has Young's modulus as low as 15.4 MPa, tensile strength as high 24.8 MPa, and elongation as long as 885%.

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Synthesis, physical properties and enzymatic degradation of bio-based poly(butylene adipate-co-butylene furandicarboxylate) copolyesters

Cited by 106 publications

References 32 publications

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Biobased poly(ethylene furanoate-co-ethylene succinate) copolyesters: solid state structure, melting point depression and biodegradability

Poly(butylene 2,5-furandicarboxylate-ε-caprolactone): A new bio-based elastomer with high strength and biodegradability

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