Synthesis, Optical, Dielectric, SHG, Magnetic and Visible Light Driven Catalytic Studies on Compounds Belonging to the Swedenborgite Structure
Sivakumar Gurusamy,
Souvik Banerjee,
Athinarayanan Sundaresan
et al.
Abstract:A new compound, InBaZn3GaO7, with swedenborgite structure along with transition metal (TM) substituted variants has been prepared. The structure contains layers of tetrahedral ions (Zn2+/Ga3+) connected by octahedrally coordinated In3+ ion forming the three‐dimensional structure with voids where the Ba2+ ions occupy. The TM substituted compounds form with new colors. The origin of the color was understood based on the ligand‐field transitions and metal to metal charge transfer (MMCT) transitions . The near IR … Show more
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