Synthesis of ZSM‐5 zeolite from fly ash by one‐pot hydrothermal method for methylene blue removal

Abstract

Using fly ash to synthesize zeolite molecular sieves can improve the reuse value of coal fly ash resources, reduce the synthesis cost of the zeolites, and protect the ecology. A novel approach was proposed to prepare zeolite socony mobil‐5 (ZSM‐5) zeolite via one‐pot hydrothermal synthesis. The mesoporous ZSM‐5 synthesized by adjusting the molar ratio of chemical reagents has higher crystallinity, larger specific surface area, and more adsorption sites. An analysis of methylene blue (MB) adsorption on mesoporous ZSM‐5 was conducted at many different adsorption parameters, including solution concentration, temperature, and duration of adsorption. The Langmuir model can objectively describe the adsorption behavior of MB on ZSM‐5, and the adsorption characteristics of MB on ZSM‐5 are better described by the pseudo‐second‐order kinetic model. The thermodynamic model provides the adsorption behavior as an endothermic reaction.

Comparative study on efficiency of surface enhanced coal fly ash and raw coal fly ash for the removal of hazardous dyes in wastewater: optimization through response surface methodology

“…This demonstrates that both types of adsorbents can sustain a high dye removal rate even after multiple uses, rendering them cost-effective and environmentally friendly solutions for dye adsorption. 65 …”