2012
DOI: 10.1039/c2jm33056c
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Synthesis of Zn2SiO4:Mn2+ by homogeneous precipitation using propylene glycol-modified silane

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Cited by 33 publications
(17 citation statements)
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“…However, using TEOS as a source of Si makes the synthesis of complex silicates with a precisely controlled chemical composition quite difficult due to the possible evaporation of TEOS during the solvent elimination process. In this study, we use a water-soluble silicon compound, known as ''propylene glycol modified silane'' (PGMS), to serve as a source of Si [19][20][21] facilitating a convenient synthesis technique for complex silicates by employing an appropriate solution-based approach. Furthermore, PGMS does not suffer from the evaporation problem like TEOS, which makes this reagent more beneficial during the synthesis of complex silicates with precisely controlled stoichiometry.…”
Section: Introductionmentioning
confidence: 99%
“…However, using TEOS as a source of Si makes the synthesis of complex silicates with a precisely controlled chemical composition quite difficult due to the possible evaporation of TEOS during the solvent elimination process. In this study, we use a water-soluble silicon compound, known as ''propylene glycol modified silane'' (PGMS), to serve as a source of Si [19][20][21] facilitating a convenient synthesis technique for complex silicates by employing an appropriate solution-based approach. Furthermore, PGMS does not suffer from the evaporation problem like TEOS, which makes this reagent more beneficial during the synthesis of complex silicates with precisely controlled stoichiometry.…”
Section: Introductionmentioning
confidence: 99%
“…PGMS was obtained by an alkoxy group exchange reaction for tetraethoxysilane with propylene glycol at 353 K in the presence of hydrochloric acid as a catalyst [11,15]. The mixed solutions were heated on a heating plate operated at 393 K with stirring to promote polymerization.…”
Section: Methodsmentioning
confidence: 99%
“…On the other hand, homogeneous distribution of the Eu 2+ activators in given host materials is one of the important factors in order to achieve high luminescence efficiency. Solution-based processes are potential methods to achieve homogeneous distribution of the activators [11][12][13][14][15][16][17][18]. Our research group recently has succeeded in improvements of emission intensities for oxynitride phosphors,…”
Section: Introductionmentioning
confidence: 99%
“…21 Mn 2+ doping Zn 2 SiO 4 have been extensively studied in the reported literature. 19,[22][23][24] Excitation and emission spectra of as prepared Zn 2 SiO 4 :0.01Mn 2+ phosphor are shown in Fig. S3.…”
Section: Luminescence Properties and Valence Analysis Of Mn Ionsmentioning
confidence: 99%