“…Panels c and d of Figure illustrate the CV and GCD curves of the as-constructed CoNi 2 S 4 //MAC ASC device, and the specific capacitance was found to be ∼155.75 F/g at 2 A/g and still appreciable at 37.2 F/g at 5 A/g (a schematic illustration of the ASC device is shown in Figure a). Remarkable energy densities of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66 kW/kg, respectively, were achieved as presented in the Ragone plot (Figure b) and found to be admirable when compared to many reports in the literature. ,,,, The stability studies were carried out for 5000 long charge–discharge cycles, which proved that the device showed a coulombic efficiency of 95.90% with a capacitance retention of 90.03%, as represented in Figure c. During the charge–discharge process in cyclic stability of an ASC, the volume of the positive electroactive material experiences a contraction and expansion process.…”
Section: Results
and Discussionmentioning
confidence: 62%
“…Remarkable energy densities of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66 kW/kg, respectively, were achieved as presented in the Ragone plot (Figure 7b) and found to be admirable when compared to many reports in the literature. 27,38,39,47,48 The stability studies were carried out for 5000 long charge−discharge cycles, which proved that the device showed a coulombic efficiency of 95.90% with a capacitance retention of 90.03%, as represented in Figure 7c.…”
Current work presents a high-performance
asymmetric supercapacitor
(ASC) using nanostructured cobalt nickel sulfide (CoNi2S4) derived via African marigold flower-like layered double
hydroxide (CoNi-LDH) as a cathode and Manihot esculenta-derived activated carbon (MAC) synthesized from oxygen-rich hydrochar
as an anode. Optimization for LDH precursors with different times
of synthesis was carried out, and best performed CoNi-LDH-12 displayed
a specific capacitance of 928 F/g at 1 A/g in a three-electrode system,
which was further sulfurized with two different sulfur ratios to obtain
CoNi2S4. As-prepared spinel CoNi2S4-800 achieved a remarkable specific capacitance of 1637
F/g at 2 A/g, and the specific capacity was found to be 184 mAh/g,
whereas the capacitance for synthesized MAC was found to be 315 F/g
at 0.5 A/g in a three-electrode system. The ASC device CoNi2S4//MAC fabricated offered remarkable energy densities
of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66
kW/kg, respectively. The prolonged cycle life studies of the ASC device
for 5000 cycles achieved a coulombic efficiency of 95.90% with a capacitance
retention of ∼90.03%, proving the electrode materials to be
promising for energy storage application.
“…Panels c and d of Figure illustrate the CV and GCD curves of the as-constructed CoNi 2 S 4 //MAC ASC device, and the specific capacitance was found to be ∼155.75 F/g at 2 A/g and still appreciable at 37.2 F/g at 5 A/g (a schematic illustration of the ASC device is shown in Figure a). Remarkable energy densities of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66 kW/kg, respectively, were achieved as presented in the Ragone plot (Figure b) and found to be admirable when compared to many reports in the literature. ,,,, The stability studies were carried out for 5000 long charge–discharge cycles, which proved that the device showed a coulombic efficiency of 95.90% with a capacitance retention of 90.03%, as represented in Figure c. During the charge–discharge process in cyclic stability of an ASC, the volume of the positive electroactive material experiences a contraction and expansion process.…”
Section: Results
and Discussionmentioning
confidence: 62%
“…Remarkable energy densities of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66 kW/kg, respectively, were achieved as presented in the Ragone plot (Figure 7b) and found to be admirable when compared to many reports in the literature. 27,38,39,47,48 The stability studies were carried out for 5000 long charge−discharge cycles, which proved that the device showed a coulombic efficiency of 95.90% with a capacitance retention of 90.03%, as represented in Figure 7c.…”
Current work presents a high-performance
asymmetric supercapacitor
(ASC) using nanostructured cobalt nickel sulfide (CoNi2S4) derived via African marigold flower-like layered double
hydroxide (CoNi-LDH) as a cathode and Manihot esculenta-derived activated carbon (MAC) synthesized from oxygen-rich hydrochar
as an anode. Optimization for LDH precursors with different times
of synthesis was carried out, and best performed CoNi-LDH-12 displayed
a specific capacitance of 928 F/g at 1 A/g in a three-electrode system,
which was further sulfurized with two different sulfur ratios to obtain
CoNi2S4. As-prepared spinel CoNi2S4-800 achieved a remarkable specific capacitance of 1637
F/g at 2 A/g, and the specific capacity was found to be 184 mAh/g,
whereas the capacitance for synthesized MAC was found to be 315 F/g
at 0.5 A/g in a three-electrode system. The ASC device CoNi2S4//MAC fabricated offered remarkable energy densities
of 55.37 and 10.66 Wh/kg at power densities of 3200 W/kg and 10.66
kW/kg, respectively. The prolonged cycle life studies of the ASC device
for 5000 cycles achieved a coulombic efficiency of 95.90% with a capacitance
retention of ∼90.03%, proving the electrode materials to be
promising for energy storage application.
“…The effect of porosity has been explained by Yang et al by preparing 3D porous architectures of NiCo-S on CC using the hydrothermal method. 108 The as-fabricated NiCo-S on CC demonstrated high specific capacitance of 1872 F g −1 at 1 A g −1 . This enhanced electrochemical performance of the asprepared electrode can be due to an increase in the specific surface areas of the material, high electrical conductivity due to the low resistance of NiCo-S, and the compact bond between NiCo-S nanowires and carbon fibers.…”
Section: D Architecture Nico-chalcogenides and Their Hybridsmentioning
confidence: 95%
“…The improved porosity helped in a faster ion intercalation/deintercalation process and reduced volume expansion trouble. The effect of porosity has been explained by Yang et al by preparing 3D porous architectures of NiCo-S on CC using the hydrothermal method . The as-fabricated NiCo-S on CC demonstrated high specific capacitance of 1872 F g –1 at 1 A g –1 .…”
Section: D Architecture Nico-chalcogenides and Their
Hybridsmentioning
Advancement in energy storage technologies is directly
related
to social development. As an advanced energy storage technology, supercapacitors
(SCs) have gained significant attention owing to their exceptional
performance in terms of energy density and power density. Electrodes
are the most important components of a supercapacitor cell; thus,
this review primarily deals with various types of transition metal-based
electrodes. Specifically, bimetallic nickel and cobalt (NiCo)-chalcogenides
and phosphides have received great attention due to their preeminent
specific capacitance, tunable electronic structure, redox chemistry,
presence of multiple oxidation states, and morphological tenability.
However, applications of these materials in practical applications
are hindered by their volumetric expansion during charge/discharge,
low rate-capability, and low cyclic stability. This review highlights
the advancement of three-dimensional (3D) NiCo-chalcogenides and phosphide
electrodes over two-dimensional (2D) electrodes as the structure tends
to improve electrocatalytic activity and stability in NiCo-based hybrid
devices. Researchers have developed a number of modifications to obtain
optimized, enhanced energy density and power density of these materials.
In addition, advances on metal organic framework (MOF)-derived 3D
architecture NiCo-chalcogenides and phosphide electrodes for SCs are
discussed in detail, and their performances are also summarized. This
report also outlines major challenges and some of the issues for increasing
the performance of SCs, and future research perspectives are suggested.
“…[22] Yang and coworkers fabricated ultrafine CoNi 2 S 4 nanowire on carbon cloth for SC electrode, which delivered a specific capacitance of 1872 F g À 1 at 1 A g À 1 and superior rate performance. [23] Yan recently presented flower-like FeCo 2 S 4 /reduced graphene oxide films, which demonstrated a high specific capacitance of 2487.97 F g À 1 with magnificent cyclic stability of 95.9 % capacitance attenuation after 5000 cycles. [24] It should be mentioned that polymer binders and conductive agents are generally used in the traditional bimetallic TMSs electrodes, which inevitably obstruct the ion-diffusion aisles, and cover the active reaction sites in electrodes, thus significantly damping the electrochemical properties.…”
The construction of integrated electrodes has been considered as a sensible strategy to boost the electrochemical properties of supercapacitors, which feature improved electron and ion transfer kinetics. In this work, a facile and easy‐controlled synthetic methodology has been established to assemble hierarchical honeycomb‐like copper‐molybdenum sulfide nanosheets (Cu−Mo−S NSs) on a three‐dimensional (3D) porous nickel foam substrate as integrated cathodes for hybrid supercapacitors (HSCs). As expected, the Cu−Mo−S NSs deliver exceptional electrochemical properties including an areal capacity of 1.39 mAh cm−2 at 2 mA cm−2, a superb rate capability (0.86 mAh cm−2 at 20 mA cm−2), and especially, a prominent cycling lifespan with 95.3 % capacity retention after 10000 cycles. Moreover, the as‐obtained Cu−Mo−S NSs are used as integrated cathodes to pair with iron oxide particles encapsulated in reduced graphene oxide (Fe2O3@rGO) as anodes for assembling Cu−Mo−S NSs//Fe2O3@rGO HSCs, which can deliver superior energy density of 79.04 Wh kg−1 and exceptional cyclic stability with 94.9 % capacity retention after 10000 cycles.
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