Type-A zeolites molecular sieve is prepared after crystallization of the type-A zeolites molecular sieve precursor, which is prepared from Stellerite, at temperature of 90 ~ 100°C for 6 hours. It has a complete structure, with crystallinity of 98%, volume average particle size of 3.72µm and particle size distribution which is less than 10µm over 90%. Multi-member rings structure in the type-A zeolites molecular sieve cover each other, forming the cage (β-cage, α-cage, octahedral cage) structure. Nuclei and nanometer particles are formed after the further congregation reaction, and then gather and grow, result in the formation of nanometer crystal particles and transformation to micrometer particles.