2014
DOI: 10.1039/c4ra09244a
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Synthesis of TiO2hollow spheres using titanium tetraisopropoxide: fabrication of high efficiency dye sensitized solar cells with photoanodes of different nanocrystalline TiO2sub-layers

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Cited by 24 publications
(5 citation statements)
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“…1 The typical structure of a DSSC consists of two sandwiched conducting glass plates; one is called a photo anode and is coated with a wide band gap and mesoporous semiconducting layer of nanoparticles with a selfassembled monolayer of chemisorbed dye molecules lled with an electrolyte for dye regeneration, and another glass plate coated with Pt, carbon, etc., is used as a counter electrode. 2 Remarkable improvements have been achieved in the performance and the maximum efficiency of DSSCs; about 11% has been reported by using liquid electrolyte and ruthenium dyes. 3 However, the major drawbacks of these solar cells are leakage of solvent, high temperature instability, dye desorption, and electrode corrosion which causes the sealing and performance degradation of DSSCs.…”
Section: Introductionmentioning
confidence: 99%
“…1 The typical structure of a DSSC consists of two sandwiched conducting glass plates; one is called a photo anode and is coated with a wide band gap and mesoporous semiconducting layer of nanoparticles with a selfassembled monolayer of chemisorbed dye molecules lled with an electrolyte for dye regeneration, and another glass plate coated with Pt, carbon, etc., is used as a counter electrode. 2 Remarkable improvements have been achieved in the performance and the maximum efficiency of DSSCs; about 11% has been reported by using liquid electrolyte and ruthenium dyes. 3 However, the major drawbacks of these solar cells are leakage of solvent, high temperature instability, dye desorption, and electrode corrosion which causes the sealing and performance degradation of DSSCs.…”
Section: Introductionmentioning
confidence: 99%
“…To carry out the LPD process, the mixture was stirred at room temperature for 24 h. The CS/TiO 2 precipitate was centrifuged and washed with ethanol and water and dried at 40 C for 10 h. Finally, the precipitate was heated at 450 C to remove the carbon templates and form the pure TiO 2 structures. 49 2.3. Instrumentation P-ASP/TOHS/MWCNT/CPE as the working electrode, Ag/AgCl 3 M KCl as the reference electrode and platinum wire as an auxiliary electrode were used for voltammetric measurements.…”
Section: Chemicals and Reagentsmentioning
confidence: 99%
“…The larger P90 TiO 2 nanoparticles could also create considerable light scattering and improve the energy conversion efficiency [62,93,94]. Nevertheless, the hydrothermally grown TiO 2 nanocrystals with sizes around 20 nm have been increasingly applied in the photoanode of DSCs in recent years [25,77,95]. The reason could be attributed to the higher surface area and higher dye loading of these nanocrystals which could increase the efficiency [50,96].…”
Section: Introductionmentioning
confidence: 97%