Synthesis of the first examples of stable heterometallic isopropoxides of an organometallic RSn(IV) moiety

Sharma, Nidhi; Singh, Anirudh; Mehrotra, R. C.

doi:10.1016/j.jorganchem.2004.08.037

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Cited by 9 publications

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“…The isopropoxy signals in (11)-(18) ( Table 4) The appearance of 27 A1 n.m.r. signals in the d 51.23-57.46 ppm region for the complexes (11)- (16) supports the presence of aluminium in four-coordinate [27,28] environment.…”

Section: Resultsmentioning

confidence: 59%

Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)

Ghadwal

Mehrotra

Singh

2005

Transition Met Chem

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Section: Resultsmentioning

confidence: 59%

Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)

Ghadwal

Mehrotra

Singh

2005

Transition Met Chem

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Synthesis and spectroscopic properties of homo– and heterobimetallic complexes of oxovanadium (V)

Ghadwal

Singh

2006

J Chem Sci

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Equimolar interaction of VO(OPr i) 3 with N-phenyldiethanolamine (H 2 L) affords the dimeric complex [VO(L)(µ-OPr i)] 2 (1), which on reaction with different glycols yields a new class of oxovanadium(V) complexes of the type: VO(L)(OGOH) (where L = C 6 H 5 N(CH 2 CH 2 O-) 2 and G = G 1 (CMe 2 CH 2 CH 2 CMe 2) 2, G 2 (CHMeCH 2 CMe 2) 3, G 3 (CH 2 CMe 2 CH 2) 4, G 4 (CH 2 CEt 2 CH 2) 5, G 5 (CHMeCHMe) 6, G 6 (CMe 2 CMe 2) 7), featuring N-phenyldiethanolaminate and glycolate moieties. Complexes (2)-(7) react with Al(OPr i) 3 to afford novel heterobimetallic coordination complexes of the type: VO(L){(OGO) Al(OPr i) 2 } (G = G 1-G 6). All these complexes have been characterised by elemental analyses and molecular weight measurements. Spectroscopic (IR, UV-Vis and (1 H, 27 Al, 51 V) NMR) properties of the new complexes have been investigated and their plausible structures suggested.

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Syntheses and crystal structures of four new organotin complexes with Schiff bases containing triazole

Hou¹,

Ma²,

Xu³

et al. 2006

Journal of Organometallic Chemistry

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Synthesis of the first examples of stable heterometallic isopropoxides of an organometallic RSn(IV) moiety

Cited by 9 publications

References 31 publications

Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)

Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)

Synthesis and spectroscopic properties of homo– and heterobimetallic complexes of oxovanadium (V)

Syntheses and crystal structures of four new organotin complexes with Schiff bases containing triazole

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