Synthesis of Some Carboxylic Acid Analogs Cleaved between the C-2 and C-3 Bond of Tetramethylcyclopropanecarboxylic Acid, and Insecticidal Activities of Their Esters

Furuhata, Akimichi; Hirano, Masachika; Fujimoto, Izumi; Matsui, Masanao

doi:10.1080/00021369.1987.10868276

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Iron-mediated Total Synthesis Of Carbazole-34-quinones2

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2002

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“…A nickel-mediated cross-coupling [175][176][177][178][179] of the 6-bromocarbazole (R)-426 with prenyl bromide and β-cyclolavandulyl bromide 425b, [225][226][227]…”

Section: Iron-mediated Total Synthesis Of Carbazole-34-quinonesmentioning

confidence: 99%

“…A nickel-mediated cross-coupling 175-179 of the 6-bromocarbazole ( R )- 426 with prenyl bromide and β-cyclolavandulyl bromide 425b , − followed by ester cleavage and oxidation with either cobalt(III) fluoride or ceric ammonium nitrate (CAN), afforded carquinostatin A [( R )- 418 ] and lavanduquinocin [( R )- 419 ], respectively (Scheme , part b).…”

Section: 1 Iron-mediated Total Synthesis Of Carbazole-34-quinonesmentioning

confidence: 99%

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Isolation and Synthesis of Biologically Active Carbazole Alkaloids

2002

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“…A nickel-mediated cross-coupling [175][176][177][178][179] of the 6-bromocarbazole (R)-426 with prenyl bromide and β-cyclolavandulyl bromide 425b, [225][226][227]…”

Section: Iron-mediated Total Synthesis Of Carbazole-34-quinonesmentioning

confidence: 99%