Synthesis of Sequence‐specific Poly(ester‐carbonate) Copolymers via Chemoselective Terpolymerization Controlled by the Stoichiometric Ratio of Phosphazene/Triethylborane
Abstract:Chemoselective terpolymerization can produce polymer materials with diverse compositions and sequential structures, and thus have attracted considerable attention in the field of polymer synthesis. However, the intrinsic complexity of three‐component system also brings great chanllenge, in regard to the reactivity and selectivity of different monomers. Herein, we report the terpolymerization of CO2/epoxide/anhydride by a binary organocatalytic C3N3‐Py‐P3/TEB (triethylborane) system. Both the activity and chemo… Show more
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