Synthesis of ROMP Monomers Containing Metal–Metal Bonds

Gilbertson, John D.; Weakley, Timothy J. R.; Han, Fusen; Wolcott, Jeffrey J.; Tyler, David R.

doi:10.1007/s10904-006-9016-0

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Mcmcoms Containing Metal‐metal Bonds1

Ring-opening Polymerization1

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Cited by 3 publications

(2 citation statements)

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“…Several cyclic metal‐metal bonded complexes with C=C were prepared and used for ROMP. Polymerization of complex 6 with Grubbs' 1st generation catalyst loading up to 10% did not yield any polymeric species . This was probably caused by the bulky phenyl groups on DPPN (DPPN: 1,2‐bis(diphenylphosphino)ethane).…”

Section: Mcmcoms Containing Metal‐metal Bondsmentioning

confidence: 99%

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Synthesis of Main‐Chain Metal Carbonyl Organometallic Macromolecules (MCMCOMs)

Cao

Murshid

Wang

2015

Macromol. Rapid Commun.

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Synthesis of main-chain metal carbonyl organometallic macromolecules (MCMCOMs) is difficult, mainly due to the instability of metal carbonyl complexes. Despite its challenge a number of MCMCOMs has been prepared by strategically using organometallic, organic, and polymer synthetic chemistry. Main contributions to this research field were reported by the groups of Tyler, Pannell, and Wang and are briefly summarized in this article.

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Section: Mcmcoms Containing Metal‐metal Bondsmentioning

confidence: 99%

“…Polymerization of complex 6 with Grubbs' 1st generation catalyst loading up to 10% did not yield any polymeric species. [ 47 ] This was probably caused by the bulky phenyl groups on DPPN (DPPN: 1,2-bis(diphenylphosphino)ethane). Consequently, the C=C in 6 could not coordinate to the catalyst preventing the polymerization.…”

Section: Ring-opening Polymerizationmentioning

confidence: 99%